Showing posts with label UV Light. Show all posts
Showing posts with label UV Light. Show all posts

Jan 7, 2024

Mysterious missing component in the clouds of Venus revealed

What are the clouds of Venus made of? Scientists know it's mainly made of sulfuric acid droplets, with some water, chlorine, and iron. Their concentrations vary with height in the thick and hostile Venusian atmosphere. But until now they have been unable to identify the missing component that would explain the clouds' patches and streaks, only visible in the UV range.

In a new study published in Science Advances, researchers from the University of Cambridge synthesised iron-bearing sulfate minerals that are stable under the harsh chemical conditions in the Venusian clouds.

Spectroscopic analysis revealed that a combination of two minerals, rhomboclase and acid ferric sulfate, can explain the mysterious UV absorption feature on our neighbouring planet.

"The only available data for the composition of the clouds were collected by probes and revealed strange properties of the clouds that so far we have been unable to fully explain," said Paul Rimmer from the Cavendish Laboratory and co-author of the study.

"In particular, when examined under UV light, the Venusian clouds featured a specific UV absorption pattern. What elements, compounds, or minerals are responsible for such observation?"

Formulated on the basis of Venusian atmospheric chemistry, the team synthesized several iron-bearing sulfate minerals in an aqueous geochemistry laboratory in the Department of Earth Sciences.

By suspending the synthesized materials in varying concentrations of sulfuric acid and monitor the chemical and mineralogical changes, the team narrowed down the candidate minerals to rhomboclase and acid ferric sulfate, of which the spectroscopic features were examined under light sources specifically designed to mimic the spectrum of solar flares (Paul Rimmer and Samantha Thompson's FlareLab at the Cavendish Laboratory).

A photochemistry lab at Harvard collaborated in the research by providing measurements of the UV absorbance patterns of ferric iron under extreme acidic conditions, in an attempt to mimic the even more extreme Venusian clouds.

The scientists are part of the newly established Origins Federation, which promotes such collaborative projects.

"The patterns and level of absorption shown by the combination of these two mineral phases are consistent with the dark UV-patches observed in Venusian clouds," said co-author Clancy Zhijian Jiang, from the Department of Earth Sciences, Cambridge.

"These targeted experiments revealed the intricate chemical network within the atmosphere, and shed light on the elemental cycling on the Venusian surface."

"Venus is our nearest neighbour, but it remains a mystery," said Rimmer.

"We will have a chance to learn much more about this planet in the coming years with future NASA and ESA missions set to explore its atmosphere, clouds and surface. This study prepares the grounds for these future explorations."

Read more at Science Daily

Jul 7, 2021

Sculpted by starlight: A meteorite witness to the solar system's birth

In 2011, scientists confirmed a suspicion: There was a split in the local cosmos. Samples of the solar wind brought back to Earth by the Genesis mission definitively determined oxygen isotopes in the sun differ from those found on Earth, the moon and the other planets and satellites in the solar system.

Early in the solar system's history, material that would later coalesce into planets had been hit with a hefty dose of ultraviolet light, which can explain this difference. Where did it come from? Two theories emerged: Either the ultraviolet light came from our then-young sun, or it came from a large nearby star in the sun's stellar nursery.

Now, researchers from the lab of Ryan Ogliore, assistant professor of physics in Arts & Sciences at Washington University in St. Louis, have determined which was responsible for the split. It was most likely light from a long-dead massive star that left this impression on the rocky bodies of the solar system. The study was led by Lionel Vacher, a postdoctoral research associate in the physics department's Laboratory for Space Sciences.

Their results are published in the journal Geochimica et Cosmochimica Acta.

"We knew that we were born of stardust: that is, dust created by other stars in our galactic neighborhood were part of the building blocks of the solar system," Ogliore said.

"But this study showed that starlight had a profound effect on our origins as well."

*Tiny time capsule

All of that profundity was packed into a mere 85 grams of rock, a piece of an asteroid found as a meteorite in Algeria in 1990, named Acfer 094. Asteroids and planets formed from the same presolar material, but they've been influenced by different natural processes. The rocky building blocks that coalesced to form asteroids and planets were broken up and battered; vaporized and recombined; and compressed and heated. But the asteroid that Acfer 094 came from managed to survive for 4.6 billion years mostly unscathed.

"This is one of the most primitive meteorites in our collection," Vacher said. "It was not heated significantly. It contains porous regions and tiny grains that formed around other stars. It is a reliable witness to the solar system's formation."

Acfer 094 is also the only meteorite that contains cosmic symplectite, an intergrowth of iron-oxide and iron-sulfide with extremely heavy oxygen isotopes -- a significant finding.

The sun contains about 6% more of the lightest oxygen isotope compared with the rest of the solar system. That can be explained by ultraviolet light shining on the solar system's building blocks, selectively breaking apart carbon monoxide gas into its constituent atoms. That process also creates a reservoir of much heavier oxygen isotopes. Until cosmic symplectite, however, no one had found this heavy isotope signature in samples of solar system materials.

With only three isotopes, however, simply finding the heavy oxygen isotopes wasn't enough to answer the question of the origin of the light. Different ultraviolet spectra could have created the same result.

"That's when Ryan came up with the idea of sulfur isotopes," Vacher said.

Sulfur's four isotopes would leave their marks in different ratios depending on the spectrum of ultraviolet light that irradiated hydrogen sulfide gas in the proto-solar system. A massive star and a young sun-like star have different ultraviolet spectra.

Cosmic symplectite formed when ices on the asteroid melted and reacted with small pieces of iron-nickel metal. In addition to oxygen, cosmic symplectite contains sulfur in iron sulfide. If its oxygen witnessed this ancient astrophysical process -- which led to the heavy oxygen isotopes -- perhaps its sulfur did, too.

"We developed a model," Ogliore said. "If I had a massive star, what isotope anomalies would be created? What about for a young, sun-like star? The precision of the model depends on the experimental data. Fortunately, other scientists have done great experiments on what happens to isotope ratios when hydrogen sulfide is irradiated by ultraviolet light."

Sulfur and oxygen isotope measurements of cosmic symplectite in Acfer 094 proved another challenge. The grains, tens of micrometers in size and a mixture of minerals, required new techniques on two different in-situ secondary-ion mass spectrometers: the NanoSIMS in the physics department (with assistance from Nan Liu, research assistant professor in physics) and the 7f-GEO in the Department of Earth and Planetary Sciences, also in Arts & Sciences.

*Putting the puzzle together


It helped to have friends in earth and planetary sciences, particularly David Fike, professor of earth and planetary sciences and director of Environmental Studies in Arts & Sciences, and Clive Jones, research scientist in earth and planetary sciences.

"They are experts in high-precision in-situ sulfur isotope measurements for biogeochemistry," Ogliore said. "Without this collaboration, we would not have achieved the precision we needed to differentiate between the young sun and massive star scenarios."

The sulfur isotope measurements of cosmic symplectite were consistent with ultraviolet irradiation from a massive star, but did not fit the UV spectrum from the young sun. The results give a unique perspective on the astrophysical environment of the sun's birth 4.6 billion years ago. Neighboring massive stars were likely close enough that their light affected the solar system's formation. Such a nearby massive star in the night sky would appear brighter than the full moon.

Today, we can look to the skies and see a similar origin story play out elsewhere in the galaxy.

"We see nascent planetary systems, called proplyds, in the Orion nebula that are being photoevaporated by ultraviolet light from nearby massive O and B stars," Vacher said.

Read more at Science Daily

Jun 15, 2021

One step towards a daily-use deep UV light source for sterilization and disinfection

Researchers from the Graduate School of Engineering and the Center for Quantum Information and Quantum Biology at Osaka University unveiled a new solid state second-harmonic generation (SHG) device that converts infrared radiation into blue light. This work may lead to a practical daily-use deep ultraviolet light source for sterilization and disinfection.

Recently, deep ultraviolet (DUV) light sources have been attracting much attention in sterilization and disinfection. In order to realize a bactericidal effect while ensuring user safety, a wavelength range of 220-230 nm is desirable. But DUV light sources in this wavelength range that are both durable and highly efficient have not yet been developed. Although wavelength conversion devices are promising candidates, conventional ferroelectric wavelength conversion materials cannot be applied to DUV devices due to absorption edge.

Since nitride semiconductors such as gallium nitride and aluminum nitride have relatively high optical nonlinearity, they can be applied to wavelength conversion devices. Due to its transparency to 210 nm, aluminum nitride is particularly suitable for DUV wavelength conversion devices. However, realizing structures with periodically inverted polarity like conventional ferroelectric wavelength conversion devices has proven quite difficult.

The researchers proposed a novel monolithic microcavity wavelength conversion device without a polarity-inverted structure. A fundamental wave is enhanced significantly in the microcavity with two distributed Bragg reflectors (DBR), and counter-propagating second harmonic waves are efficiently emitted in phase from the one side. As the first step towards a practical DUV light source, a gallium nitride microcavity device was fabricated via microfabrication technology, including dry etching and anisotropic wet etching for vertical and smooth DBR sidewalls. By obtaining a blue SH wave, the effectiveness of the proposed concept was successfully demonstrated.

"Our device can be adapted to use a broader range of materials. They can be applied to deep ultraviolet light emission or even broadband photon pair generation," senior author Masahiro Uemukai says. The researchers hope that because this approach does not rely on materials or periodically inverted structures, it will make future nonlinear optical devices easier to construct.

From Science Daily