Showing posts with label Metal Oxide. Show all posts
Showing posts with label Metal Oxide. Show all posts

Jan 25, 2023

Reducing steel corrosion vital to combating climate change

Every year, the United States spends nearly a trillion dollars fighting metallic corrosion, an electrochemical reaction that occurs when metals oxidize and begin to rust. By taking on this surprisingly insidious issue, researchers have now estimated how much corrosion is gradually worsening global carbon emissions.

Global steel production has been rising steadily for decades -- and because steel has poor resistance to corrosion, part of that demand is to replace steel used in construction materials that have become corroded over time, in everything from bridges to automobiles. Reducing the amount of steel that needs to be replaced due to corrosion could have measurable effects on how much greenhouse gases are produced to make steel, said Gerald Frankel, co-author of the study and a professor in materials science and engineering at The Ohio State University,

Though previous studies have estimated the current economic cost of corrosion to be about 3 to 4% of a nation's gross domestic product, this new study, led by Ohio State alum Mariano Iannuzzi, is the first to quantify the environmental impact associated with steel corrosion.

The study was recently published in the journalnpj Materials Degradation.

"Given society's reliance on coal fuel, iron and steel production is one of the largest greenhouse gases emitters of any industry," said Frankel. "But most of the costs associated with the industry actually stem from the energy that goes into creating steel, and that energy is lost as the steel reverts to rust, which is similar to its original form of iron ore."

The time it takes steel to corrode largely depends on the severity of the environment and the alloy composition, but this environmentally expensive issue is only getting worse, said Frankel.

Using historical carbon dioxide intensity data to estimate carbon dioxide levels per year beginning from 1960, the researchers found that in 2021, steel production accounted for 27% of the carbon emissions of the global manufacturing sector, and about 10.5% of the total global carbon emissions worldwide. Corroded steel replacement accounted for about 1.6 to 3.4% of emissions.

But there is some good news, the study noted. Due to regulations placed on the steel industry, technological advances in the steelmaking process have resulted in a 61% reduction in energy consumption over the last 50 years.

Despite this improvement, the results of the study are a call to action for policymakers and industry officials to amend and coordinate international policy regarding steel production and corrosion management, Frankel said.

"Coordinated international strategies, as well as decreasing global steel demand, by using best practices for corrosion mitigation, could better improve global corrosion management strategies and drastically reduce the rise in greenhouse gas emissions we're seeing due to repeatedly replacing corroded steel," he said.

If actions to improve steel's carbon footprint aren't taken soon, the study notes that greenhouse gas emissions produced by the steel industry could reach about 27.5% of the world's total carbon emissions by 2030, with corroded steel representing about 4 to 9% of that number. Such a result would make the goals set by the Paris Agreement to limit Earth's warming to 1.5 degrees Celsius as well as the U.S.'s own domestic climate goals almost completely unfeasible. The study notes that management strategies such as taking advantage of machine learning technologies could be one of the best chances we have to reduce Earth's carbon dioxide levels.

That said, if humans cannot meet these conditions, the consequences for Earth's climate will be dire, so more people need to be made aware that a low-carbon steel industry is needed to prevent such a dystopia, said Frankel.

Read more at Science Daily

Apr 4, 2022

Solar hydrogen: Better photoelectrodes through flash heating

Solar energy can directly drive electrochemical reactions at the surface of photoelectrodes. Photoelectrodes consist of semiconducting thin films on transparent conductive-glass substrates that convert light into electricity. Most photoelectrochemical studies have focused on water splitting, a thermodynamically uphill reaction that could offer an attractive pathway for the long-term capture and storage of solar energy by producing 'green' hydrogen.

Metal-oxide thin film photoelectrodes are particularly promising for these diverse functions. They comprise abundant elements, potentially offering infinite tunability to achieve the desired properties -- at potentially low costs.

Made from plasma

At the HZB Institute for Solar Fuels, several teams focus on developing such photoelectrodes. The usual method to produce them is pulsed laser deposition: an intense laser pulse hits a target containing the material and ablates it into a highly energetic plasma deposited on a substrate.

Quality needs heat

Further steps are needed to improve the quality of the deposited thin film. In particular thermal processing of the metal-oxide thin-film reduces defects and imperfections. However, this creates a dilemma: Reducing atomic defects concentration and improvements in crystalline order of the metal-oxide thin films would require thermal processing temperatures between 850 and 1000 degrees Celsius -- but the problem is that the glass substrate melts at 550 degrees Celsius.

Flash-heating the thin film

Dr. Ronen Gottesman from the HZB Institute for Solar Fuels has now solved this problem: After deposition, using high-powered lamps, he flash-heats the metal-oxide thin film. This heats it up to 850 degrees Celsius without melting the underlying glass substrate.

"The heat efficiently reduces structural defects, trap states, grain boundaries, and phase impurities, which would become more challenging to mitigate with an increasing number of elements in the metal-oxides. Therefore, new innovative synthesis approaches are essential. We have now demonstrated this on photoelectrodes made of Ta2O5, TiO2, and WO3, which we heated to 850 °C without damaging the substrates," says Gottesman.

Record performance for α-SnWO4

The new method was also successful with a photoelectrode material that is considered a very good candidate for solar water splitting: α-SnWO4. Conventional furnace heating leaves behind phase impurities. Rapid thermal processing (RTP) heating improved crystallinity, electronic properties, and performance, leading to a new record performance of 1 mA/cm2 for this material, higher by 25% than the previous record.

Read more at Science Daily