New field of research: Crystal traces in fossil leaves

Fossil specimen Ro-59.9 is littered with microscopic cavities. Some of them look as if tiny raspberries had once slumbered inside them, each of them just two hundredths of a millimeter in size. The fossilized leaf comes from the Rott fossil site near Bonn and is more than 20 million years old. At the moment, it is not possible to say to which plant species it belongs.

Perhaps that will change soon. Because the position and shape of the cavities are like a kind of fingerprint: they can be used to identify fossil plant remains. "Until now, it was not known how these cavities were formed," explains Mahdieh Malekhosseini from the Institute of Geosciences at the University of Bonn. "For example, it was believed that they came from algae or pollen from other plants that somehow got onto the leaf during fossilization. But after analyzing hundreds of these structures, we can rule that out. Instead, we were able to show that calcium oxalate crystals are responsible for the depressions."

Microlenses for better photosynthesis?

Calcium oxalate is formed by very many living plants; it is considered one of the most common biominerals. What functions it fulfills has not yet been conclusively clarified. However, it is suspected that the crystals serve as calcium stores. In addition, because they are formed in the leaf but often penetrate the leaf surface as they grow, they probably repel pests. "Many insects have an aversion to calcium oxalate -- they don't like to walk on it," explains Prof. Dr. Jes Rust, who supervised the study. "Some plants also seem to use the crystals as microlenses to use sunlight more efficiently for photosynthesis."

The crystals are very sensitive to acid. They therefore dissolve during fossilization and can no longer be detected in the millions of years old finds. Often, however, imprints remain in the places where they have sat (in biology one speaks of "druses"). Sometimes organic material or other minerals also accumulate in these depressions, which then sit like tiny beads in the fossil leaf.

"We studied the microstructure of the pits and their distribution on fossil leaves whose species affiliation we knew," Malekhosseini explains. "In addition, we looked at calcium oxalate crystals in the leaves of present-day plants. We found clear parallels in closely related species. For example, the crystal imprints in a fossil ginkgo leaf strongly resemble the calcium oxalate deposits of a present-day ginkgo in distribution and structure."

Important insights into evolution

It was already known from the fossils of bare-seeded plants such as firs or pines that they sometimes show imprints of calcium oxalate crystals. However, this was not known of angiosperms -- which are most flowers and deciduous trees. "This is a completely new field of research," explains Jes Rust. "Among other things, we now want to investigate how the ability to form calcium oxalate crystals has developed over the course of evolution." In doing so, the researchers want to focus on periods when environmental conditions changed rapidly -- such as temperature or the intensity of UV radiation. "If the distribution of the drusen also changes after such incisions, then we can draw conclusions about the biological function of the crystals," says Rust.

Read more at Science Daily

Time crystals 'impossible' but obey quantum physics

Scientists have created the first "time-crystal" two-body system in an experiment that seems to bend the laws of physics.

It comes after the same team recently witnessed the first interaction of the new phase of matter.

Time crystals were long believed to be impossible because they are made from atoms in never-ending motion. The discovery, published in Nature Communications, shows that not only can time crystals be created, but they have potential to be turned into useful devices.

Time crystals are different from a standard crystal -- like metals or rocks -- which is composed of atoms arranged in a regularly repeating pattern in space.

First theorised in 2012 by Nobel Laureate Frank Wilczek and identified in 2016, time crystals exhibit the bizarre property of being in constant, repeating motion in time despite no external input. Their atoms are constantly oscillating, spinning, or moving first in one direction, and then the other.

EPSRC Fellow Dr Samuli Autti, lead author from Lancaster University's Department of Physics, explained: "Everybody knows that perpetual motion machines are impossible. However, in quantum physics perpetual motion is okay as long as we keep our eyes closed. By sneaking through this crack we can make time crystals."

"It turns out putting two of them together works beautifully, even if time crystals should not exist in the first place. And we already know they also exist at room temperature."

A "two-level system" is a basic building block of a quantum computer. Time crystals could be used to build quantum devices that work at room temperature.

An international team of researchers from Lancaster University, Royal Holloway London, Landau Institute, and Aalto University in Helsinki observed time crystals by using Helium-3 which is a rare isotope of helium with one missing neutron. The experiment was carried out in Aalto University.

Read more at Science Daily

Earliest geochemical evidence of plate tectonics found in 3.8-billion-year-old crystal

A handful of ancient zircon crystals found in South Africa hold the oldest evidence of subduction, a key element of plate tectonics, according to a new study published today in AGU Advances, AGU's journal for high-impact, open-access research and commentary across the Earth and space sciences.

These rare time capsules from Earth's youth point to a transition around 3.8 billion years ago from a long-lived, stable rock surface to the active processes that shape our planet today, providing a new clue in a hot debate about when plate tectonics was set in motion.

Earth's crust and the top layer of mantle just under it are broken up into rigid plates that move slowly on top of viscous but mobile lower layers of mantle rock. Heat from Earth's core drives this slow but inexorable motion, responsible for volcanoes, earthquakes, and the uplift of mountain ranges.

Estimates for when this process revved up and modern crust formed range from over 4 billion years ago to just 800 million years ago. Uncertainty arises because the geologic record from Earth's youth is sparse, due to the surface recycling effect of plate tectonics itself. Almost nothing remains from the Hadean Eon, Earth's first 500 million years.

"The Hadean Earth is this big mystery box," said Nadja Drabon, a geologist at Harvard University and the lead author of the new study.

Tiny time capsules

In an exciting step forward in solving this mystery, in 2018 Drabon and her colleagues unearthed a chronological series of 33 microscopic zircon crystals from a rare, ancient block of crust in the Barberton Greenstone Belt in South Africa, that formed at different times over a critical 800-million-year span from 4.15 to 3.3 billion years ago.

Zircon is a relatively common accessory mineral in Earth's crust, but ancient representatives from the Hadean Eon, 4 to 4.56 billion years ago, are exceedingly rare, found in only 12 places on Earth, and usually in numbers fewer than three at each location.

Hafnium isotopes and trace elements preserved in the Greenstone Belt zircons told a story about the conditions on Earth at the time they crystalized. Zircons 3.8-billion-years-old and younger appeared to have formed in rock experiencing pressures and melting similar to modern subduction zones, suggesting the crust may have started moving.

"When I say plate tectonics, I'm specifically referring to an arc setting, when one plate goes under another and you have all that volcanism -- think of the Andes, for example, and the Ring of Fire," Drabon said, describing a classic example of subduction.

"At 3.8 billion years there is a dramatic shift where the crust is destabilized, we have new rocks forming and we see geochemical signatures becoming more and more similar to what we see in modern plate tectonics," Drabon said.

In contrast, the older zircons preserved evidence of a global cap of "protocrust" derived from remelting mantle rock that had remained stable for 600 million years, the study found.

Signs of global change

The new study found a similar transition to conditions resembling modern subduction in zircons from other locations around the world, dating to within about 200 million years of the South African zircons.

"We see evidence for a significant change on the Earth around 3.8 to 3.6 billion years ago and evolution toward plate tectonics is one clear possibility." Drabon said.

While not conclusive, the results suggest a global change may have begun, Drabon said, possibly starting and stopping in scattered locations before settling into the efficient global engine of constantly moving plates we see today.

Plate tectonics shapes Earth's atmosphere as well as its surface. Release of volcanic gasses and production of new silicate rock, which consumes large amounts carbon dioxide from the atmosphere, temper large temperature swings from too much or too little greenhouse gas.

"Without all of the recycling and new crust forming, we might be going back and forth between boiling hot and freezing cold," Drabon said. "It's kind of like a thermostat for the climate."

Plate tectonics has, so far, only been observed on Earth, and may be essential to making a planet livable, Drabon said, which makes the origins of plate motions of interest in research into the early development of life.

Read more at Science Daily

Time crystals leave the lab

We have all seen crystals, whether a simple grain of salt or sugar, or an elaborate and beautiful amethyst. These crystals are made of atoms or molecules repeating in a symmetrical three-dimensional pattern called a lattice, in which atoms occupy specific points in space. By forming a periodic lattice, carbon atoms in a diamond, for example, break the symmetry of the space they sit in. Physicists call this "breaking symmetry."

Scientists have recently discovered that a similar effect can be witnessed in time. Symmetry breaking, as the name suggests, can arise only where some sort of symmetry exists. In the time domain, a cyclically changing force or energy source naturally produces a temporal pattern.

Breaking of the symmetry occurs when a system driven by such a force faces a déjà vu moment, but not with the same period as that of the force. 'Time crystals' have in the past decade been pursued as a new phase of matter, and more recently observed under elaborate experimental conditions in isolated systems. These experiments require extremely low temperatures or other rigorous conditions to minimize undesired external influences, called noise.

In order for scientists to learn more about time crystals and employ their potential in technology, they need to find ways to produce time crystalline states and keep them stable outside the laboratory.

Cutting-edge research led by UC Riverside and published this week in Nature Communications has now observed time crystals in a system that is not isolated from its ambient environment. This major achievement brings scientists one step closer to developing time crystals for use in real-world applications.

"When your experimental system has energy exchange with its surroundings, dissipation and noise work hand-in-hand to destroy the temporal order," said lead author Hossein Taheri, an assistant research professor of electrical and computer engineering in UC Riverside's Marlan and Rosemary Bourns College of Engineering. "In our photonic platform, the system strikes a balance between gain and loss to create and preserve time crystals."

The all-optical time crystal is realized using a disk-shaped magnesium fluoride glass resonator one millimeter in diameter. When bombarded by two laser beams, the researchers observed subharmonic spikes, or frequency tones between the two laser beams, that indicated breaking of temporal symmetry and creation of time crystals.

The UCR-led team utilized a technique called self-injection locking of the two lasers to the resonator to achieve robustness against environmental effects. Signatures of the temporally repeating state of this system can readily be measured in the frequency domain. The proposed platform therefore simplifies the study of this new phase of matter.

Without the need for a low temperature, the system can be moved outside a complex lab for field applications. One such application could be highly accurate measurements of time. Because frequency and time are mathematical inverses of each other, accuracy in measuring frequency enables accurate time measurement.

"We hope that this photonic system can be utilized in compact and lightweight radiofrequency sources with superior stability as well as in precision timekeeping," said Taheri.

Read more at Science Daily

Researchers trace dust grain's journey through newborn solar system

A research team led by the University of Arizona has reconstructed in unprecedented detail the history of a dust grain that formed during the birth of the solar system more than 4.5 billion years ago. The findings provide insights into the fundamental processes underlying the formation of planetary systems, many of which are still shrouded in mystery.

For the study, the team developed a new type of framework, which combines quantum mechanics and thermodynamics, to simulate the conditions to which the grain was exposed during its formation, when the solar system was a swirling disk of gas and dust known as a protoplanetary disk or solar nebula. Comparing the predictions from the model to an extremely detailed analysis of the sample's chemical makeup and crystal structure, along with a model of how matter was transported in the solar nebula, revealed clues about the grain's journey and the environmental conditions that shaped it along the way.

The grain analyzed in the study is one of several inclusions, known as calcium-aluminum rich inclusions, or CAIs, discovered in a sample from the Allende meteorite, which fell over the Mexican state of Chihuahua in 1969. CAIs are of special interest because they are thought to be among the first solids that formed in the solar system more than 4.5 billion years ago.

Similar to how stamps in a passport tell a story about a traveler's journey and stops along the way, the samples' micro- and atomic-scale structures unlock a record of their formation histories, which were controlled by the collective environments to which they were exposed.

"As far as we know, our paper is the first to tell an origin story that offers clues about the likely processes that happened at the scale of astronomical distances with what we see in our sample at the scale of atomic distances," said Tom Zega, a professor in the University of Arizona's Lunar and Planetary Laboratory and the first author of the paper, published in The Planetary Science Journal.

Zega and his team analyzed the composition of the inclusions embedded in the meteorite using cutting-edge atomic-resolution scanning transmission electron microscopes -- one at UArizona's Kuiper Materials Imaging and Characterization Facility, and its sister microscope located at the Hitachi factory in Hitachinaka, Japan.

The inclusions were found to consist mainly of types of minerals known as spinel and perovskite, which also occur in rocks on Earth and are being studied as candidate materials for applications such as microelectronics and photovoltaics.

Similar kinds of solids occur in other types of meteorites known as carbonaceous chondrites, which are particularly interesting to planetary scientists as they are known to be leftovers from the formation of the solar system and contain organic molecules, including those that may have provided the raw materials for life.

Precisely analyzing the spatial arrangement of atoms allowed the team to study the makeup of the underlying crystal structures in great detail. To the team's surprise, some of the results were at odds with current theories on the physical processes thought to be active inside protoplanetary disks, prompting them to dig deeper.

"Our challenge is that we don't know what chemical pathways led to the origins of these inclusions," Zega said. "Nature is our lab beaker, and that experiment took place billions of years before we existed, in a completely alien environment."

Zega said the team set out to "reverse-engineer" the makeup of the extraterrestrial samples by designing new models that simulated complex chemical processes, which the samples would be subjected to inside a protoplanetary disk.

"Such models require an intimate convergence of expertise spanning the fields of planetary science, materials science, mineral science and microscopy, which was what we set out to do," added Krishna Muralidharan, a study co-author and an associate professor in the UArizona's Department of Materials Science and Engineering.

Based on the data the authors were able to tease from their samples, they concluded that the particle formed in a region of the protoplanetary disk not far from where Earth is now, then made a journey closer to the sun, where it was progressively hotter, only to later reverse course and wash up in cooler parts farther from the young sun. Eventually, it was incorporated into an asteroid, which later broke apart into pieces. Some of those pieces were captured by Earth's gravity and fell as meteorites.

The samples for this study were taken from the inside of a meteorite and are considered primitive -- in other words, unaffected by environmental influences. Such primitive material is believed to not have undergone any significant changes since it first formed more than 4.5 billion years ago, which is rare. Whether similar objects occur in asteroid Bennu, samples of which will be returned to Earth by the UArizona-led OSIRIS-REx mission in 2023, remains to be seen. Until then, scientists rely on samples that fall to Earth via meteorites.

"This material is our only record of what happened 4.567 billion years ago in the solar nebula," said Venkat Manga, a co-author of the paper and an assistant research professor in the UArizona Department of Materials Science and Engineering. "Being able to look at the microstructure of our sample at different scales, down to the length of individual atoms, is like opening a book."

The authors said that studies like this one could bring planetary scientists a step closer to "a grand model of planet formation" -- a detailed understanding of the material moving around the disk, what it is composed of, and how it gives rise to the sun and the planets.

Powerful radio telescopes like the Atacama Large Millimeter/submillimeter Array, or ALMA, in Chile now allow astronomers to see stellar systems as they evolve, Zega said.

"Perhaps at some point we can peer into evolving disks, and then we can really compare our data between disciplines and begin answering some of those really big questions," Zega said. "Are these dust particles forming where we think they did in our own solar system? Are they common to all stellar systems? Should we expect the pattern we see in our solar system -- rocky planets close to the central star and gas giants farther out -- in all systems?

Read more at Science Daily

Organic crystals' ice-forming superpowers

 At the heart of clouds are ice crystals. And at the heart of ice crystals, often, are aerosol particles -- dust in the atmosphere onto which ice can form more easily than in the open air.

It's a bit mysterious how this happens, though, because ice crystals are orderly structures of molecules, while aerosols are often disorganized chunks. New research by Valeria Molinero, distinguished professor of chemistry, and Atanu K. Metya, now at the Indian Institute of Technology Patna, shows how crystals of organic molecules, a common component of aerosols, can get the job done.

The story is more than that, though -- it's a throwback to Cold War-era cloud seeding research and an investigation into a peculiar memory effect that sees ice form more readily on these crystals the second time around.

The research, funded by the Air Force Office of Scientific Research, is published in the Journal of the American Chemical Society.

Throwback to cloud seeding

Molinero's research is focused on how ice forms, particularly the process of nucleation, which is the beginning of ice crystal formation. Under the right conditions, water molecules can nucleate ice on their own. But often some other material, called a nucleant, can help the process along.

After several studies on the ways that proteins can help form ice, Molinero and Metya turned their attention to organic ice nucleants (as used here, "organic" means organic compounds containing carbon) because they are similar to the ice-producing proteins and are found in airborne aerosols.

But a review of the scientific literature found that the papers discussing ice nucleation by organic compounds came from the 1950s and 1960s, with very little follow-up work after that until very recently.

"That made me really curious," Molinero says, "because there is a lot of interest now on organic aerosols and whether and how they promote the formation of ice in clouds, but all this new literature seemed dissociated from these early fundamental studies of organic ice nucleants."

Additional research revealed that the early work on organic ice nucleants was related to the study of cloud seeding, a post-war line of research into how particles (primarily silver iodide) could be introduced into the atmosphere to encourage cloud formation and precipitation. Scientists explored the properties of organic compounds as ice nucleants to see if they might be cost-effective alternatives to silver iodide.

But cloud seeding research collapsed in the 1970s after political pressures and fears of weather modification led to a ban on the practice in warfare. Funding and interest in organic ice nucleants dried up until recently, when climate research spurred a renewed interest in the chemistry of ice formation in the atmosphere.

"There has been a growing interest in ice nucleation by organic aerosols in the last few years, but no connection to these old studies on organic crystals," Molinero says. "So, I thought it was time to "rescue" them into the modern literature."

Going all classic

Phloroglucinol is one of the organic nucleants studied in the mid-20th century. It showed promise for controlling fog, but less for cloud seeding. Molinero and Metya revisited phloroglucinol as it proved potent at ice nucleation in the lab.

One question to answer is whether phloroglucinol nucleates ice through classical or non-classical processes. When ice nucleates on its own, without any surfaces or other molecules, the only hurdle to overcome is forming a stable crystallite of ice (only about 500 molecules in size under some conditions) that other molecules can build on to grow an ice crystal. That's classical nucleation.

Non-classical nucleation, involving a nucleant surface, occurs when a layer of water molecules assembles on the surface on which other water molecules can organize into a crystal lattice. The hurdle to overcome in non-classical nucleation is the formation of the monolayer.

Which applies to phloroglucinol? In the 1960s, researcher L.F. Evans concluded that it was non-classical. "I am still amazed he was able to deduce the existence of a monolayer and infer the mechanism was non-classical from experiments of freezing as a function of temperature alone!" Molinero says. But Molinero and Metya, using molecular simulations of how ice forms, found that it's more complicated.

"We find that the step that really decides whether water transforms to ice or not is not the formation of the monolayer but the growth of an ice crystallite on top," Molinero says. "That makes ice formation by organics classical although no less fascinating."

Holding on to memories of ice

The researchers also used their simulation methods to investigate an interesting memory effect previously observed with organic and other nucleants. When ice is formed, melted and formed again using these nucleants, the second round of crystallization is more effective than the first. It's assumed that the ice melts completely between crystallizations, and researchers have posed several potential explanations.

Molinero and Metya found that the memory effect isn't due to the ice changing the nucleant surface, nor to the monolayer of water persisting on the nucleant surface after melting. Instead, their simulations supported an explanation where crevices in the nucleant can hold on to small amounts of ice that melt at higher temperatures than the rest of the ice in the experiment. If these crevices are adjacent to one of the nucleant crystal surfaces that's good at forming ice, then it's off to the races when the second round of freezing begins.

Something in the air

Other mysteries still remain -- the mid-century studies of organic crystals found that at high pressures, around 1500 times atmospheric pressure, that the crystals are as efficient at organizing water molecules into ice as an ice crystal itself. Why? That's the focus of Molinero's next experiments.

More immediately, though, phloroglucinol is a naturally-occurring compound in the atmosphere, so anything that researchers can learn about it and other organic nucleants can help explain the ability of aerosols to nucleate ice and regulate the formation of clouds and precipitation.

Read more at Science Daily

New crystalline form of ice

 Three years ago, chemists found evidence for the existence of a new variety of ice. Until then, 18 types of crystalline ice were known. The team now reports on the elucidation of the crystal structure of ice XIX using neutron diffraction.

Ice is a very versatile material. In snowflakes or ice cubes, the oxygen atoms are arranged hexagonally. This ice form is called ice one (ice I). "Strictly speaking, however, these are not actually perfect crystals, but disordered systems in which the water molecules are randomly oriented in different spatial directions," explains Thomas Loerting from the Institute of Physical Chemistry at the University of Innsbruck, Austria. Including ice I, 18 crystalline forms of ice were known so far, which differ in the arrangement of their atoms. The different types of ice, known as polymorphs, form depending on pressure and temperature and have very different properties. For example, their melting points differ by several hundred degrees Celsius. "It's comparable to diamond and graphite, both of which are made of pure carbon," the chemist explains.

Icy variety

When conventional ice I is cooled strongly, the hydrogen atoms can arrange themselves periodically in addition to the oxygen atoms if the experiment is conducted correctly. Below minus 200 degrees Celsius, this can lead to the formation of so-called ice XI, in which all water molecules are ordered according to a specific pattern. Such ordered ice forms differ from the disordered parental forms, especially in their electrical properties. In the current work, the Innsbruck chemists deal with the parent form ice VI, which is formed at high pressure, for example in the Earth's mantle. Like hexagonal ice, this high-pressure form of ice is not a completely ordered crystal. More than 10 years ago, researchers at the University of Innsbruck produced a hydrogen-ordered variant of this ice, which found its way into textbooks as ice XV. By changing the manufacturing process, three years ago Thomas Loerting's team succeeded for the first time in creating a second ordered form for ice VI. To do this, the scientists significantly slowed down the cooling process and increased the pressure to around 20 kbar. This enabled them to arrange the hydrogen atoms in a second way in the oxygen lattice and produce ice XIX. "We found clear evidence at that time that it is a new ordered variant, but we were not able to elucidate the crystal structure." Now his team has succeeded in doing just that using the gold standard for structure determination -- neutron diffraction.

Crystal structure solved

For the clarification of the crystal structure, an essential technical hurdle had to be overcome. In an investigation using neutron diffraction, it is necessary to replace the light hydrogen in water with deuterium ("heavy hydrogen"). "Unfortunately, this also changes the time scales for ordering in the ice manufacturing process," says Loerting. "But Ph.D. student Tobias Gasser then had the crucial idea of adding a few percent of normal water to the heavy water -- which turned out to speed up the ordering immensely." With the ice obtained in this way, the Innsbruck scientists were finally able to measure neutron data on the high-resolution HRPD instrument at the Rutherford Appleton Laboratory in England and painstakingly solve the crystal structure of ice XIX. This required finding the best crystal structure out of several thousand candidates from the measured data -- much like searching for a needle in a haystack. A Japanese research group confirmed the Innsbruck result in another experiment under different pressure conditions. Both papers have now been published jointly in Nature Communications.

Six ice forms discovered in Innsbruck

While conventional ice and snow are abundant on Earth, no other forms are found on the surface of our planet -- except in research laboratories. However, the high-pressure forms ice VI and ice VII are found as inclusions in diamonds and have therefore been added to the list of minerals by the International Mineralogical Association (IMA). Many varieties of water ice are formed in the vastness of space under special pressure and temperature conditions. They are found, for example, on celestial bodies such as Jupiter's moon Ganymede, which is covered by layers of different ice varieties.

Ice XV and ice XIX represents the first sibling pair in ice physics in which the oxygen lattice is the same, but the pattern how hydrogen atoms are ordered is different. "This also means that for the first time it will now be possible to realize the transition between two ordered ice forms in experiments," Thomas Loerting is pleased to report. Since the 1980s, researchers at the University of Innsbruck, Austria, are now responsible for the discovery of four crystalline as well as two amorphous ice forms.

Read more at Science Daily

Scientists create liquid crystals that look a lot like their solid counterparts

 A team at the University of Colorado Boulder has designed new kinds of liquid crystals that mirror the complex structures of some solid crystals -- a major step forward in building flowing materials that can match the colorful diversity of forms seen in minerals and gems, from lazulite to topaz.

The group's findings, published today in the journal Nature, may one day lead to new types of smart windows and television or computer displays that can bend and control light like never before.

The results come down to a property of solid crystals that will be familiar to many chemists and gemologists: Symmetry.

Ivan Smalyukh, a professor in the Department of Physics at CU Boulder, explained that scientists categorize all known crystals into seven main classes, plus many more sub-classes -- in part based on the "symmetry operations" of their internal atoms. In other words, how many ways can you stick an imaginary mirror inside of a crystal or rotate it and still see the same structure? Think of this classification system as Baskin-Robbins' 32 flavors but for minerals.

To date, however, scientists haven't been able to create liquid crystals -- flowing materials that are found in most modern display technologies -- that come in those same many flavors.

"We know everything about all the possible symmetries of solid crystals that we can make. There are 230 of them," said Smalyukh, senior author of the new study who is also a fellow of the Renewable and Sustainable Energy Institute (RASEI) at CU Boulder. "When it comes to nematic liquid crystals, the kind in most displays, we only have a few that have been demonstrated so far."

That is, until now.

In their latest findings, Smalyukh and his colleagues came up with a way to design the first liquid crystals that resemble monoclinic and orthorhombic crystals -- two of those seven main classes of solid crystals. The findings, he said, bring a bit more of order to the chaotic world of fluids.

"There are a lot of possible types of liquid crystals, but, so far, very few have been discovered," Smalyukh said. "That is great news for students because there's a lot more to find."

Symmetry in action

To understand symmetry in crystals, first picture your body. If you place a giant mirror running down the middle of your face, you'll see a reflection that looks (more or less) like the same person.

Solid crystals have similar properties. Cubic crystals, which include diamonds and pyrite, for example, are made up of atoms arranged in the shape of a perfect cube. They have a lot of symmetry operations.

"If you rotate those crystals by 90 or 180 degrees around many special axes, for example, all of the atoms stay in the right places," Smalyukh said.

But there are other types of crystals, too. The atoms inside monoclinic crystals, which include gypsum or lazulite, are arranged in a shape that looks like a slanted column. Flip or rotate these crystals all you want, and they still have only two distinct symmetries -- one mirror plane and one axis of 180-degree rotation, or the symmetry that you can see by spinning a crystal around an axis and noticing that it looks the same every 180 degrees. Scientists call that a "low-symmetry" state.

Traditional liquid crystals, however, don't display those kinds of complex structures. The most common liquid crystals, for example, are made up of tiny rod-shaped molecules. Under the microscope, they tend to line up like dry pasta noodles tossed into a pot, Smalyukh said.

"When things can flow they don't usually exhibit such low symmetries," Smalyukh said.

Order in liquids

He and his colleagues wanted to see if they could change that. To begin, the team mixed together two different kinds of liquid crystals. The first was the common class made up of rod-shaped molecules. The second was made up of particles shaped like ultra-thin disks.

When the researchers brought them together, they noticed something strange: Under the right conditions in the lab, those two types of crystals pushed and squeezed each other, changing their orientation and arrangement. The end result was a nematic liquid crystal fluid with symmetry that looks a lot like that of a solid monoclinic crystal. The molecules inside displayed some symmetry, but only one mirror plane and one axis of 180-degree rotation.

The group had created, in other words, a material with the mathematical properties of a lazulite or gypsum crystal -- but theirs could flow like a fluid.

"We're asking a very fundamental question: What are the ways that you can combine order and fluidity in a single material?" Smalyukh said.

And, the team's creations are dynamic: If you heat the liquid crystals up or cool them down, for example, you can morph them into a rainbow of different structures, each with their own properties, said Haridas Mundoor, lead author of the new paper. That's pretty handy for engineers.

"This offers different avenues that can modify display technologies, which may enhance the energy efficiency in performance of devices like smart phones," said Mundoor, a postdoctoral research associate at CU Boulder.

He and his colleagues are still nowhere near making liquid crystals that can replicate the full spectrum of solid crystals. But the new paper gets them closer than ever before -- good news for fans of shiny things everywhere.

Read more at Science Daily

Meteorite strikes may create unexpected form of silica

 When a meteorite hurtles through the atmosphere and crashes to Earth, how does its violent impact alter the minerals found at the landing site? What can the short-lived chemical phases created by these extreme impacts teach scientists about the minerals existing at the high-temperature and pressure conditions found deep inside the planet?

New work led by Carnegie's Sally June Tracy examined the crystal structure of the silica mineral quartz under shock compression and is challenging longstanding assumptions about how this ubiquitous material behaves under such intense conditions. The results are published in Science Advances.

"Quartz is one of the most abundant minerals in Earth's crust, found in a multitude of different rock types," Tracy explained. "In the lab, we can mimic a meteorite impact and see what happens."

Tracy and her colleagues -- Washington State University's (WSU) Stefan Turneaure and Princeton University's Thomas Duffy, a former Carnegie Fellow -- used a specialized cannon-like gas gun to accelerate projectiles into quartz samples at extremely high speeds -- several times faster than a bullet fired from a rifle. Special x-ray instruments were used to discern the crystal structure of the material that forms less than one-millionth of a second after impact. Experiments were carried out at the Dynamic Compression Sector (DCS), which is operated by WSU and located at the Advanced Photon Source, Argonne National Laboratory.

Quartz is made up of one silicon atom and two oxygen atoms arranged in a tetrahedral lattice structure. Because these elements are also common in the silicate-rich mantle of the Earth, discovering the changes quartz undergoes at high-pressure and -temperature conditions, like those found in the Earth's interior, could also reveal details about the planet's geologic history.

When a material is subjected to extreme pressures and temperatures, its internal atomic structure can be re-shaped, causing its properties to shift. For example, both graphite and diamond are made from carbon. But graphite, which forms at low pressure, is soft and opaque, and diamond, which forms at high pressure, is super-hard and transparent. The different arrangements of carbon atoms determine their structures and their properties, and that in turn affects how we engage with and use them.

Despite decades of research, there has been a long-standing debate in the scientific community about what form silica would take during an impact event, or under dynamic compression conditions such as those deployed by Tracy and her collaborators. Under shock loading, silica is often assumed to transform to a dense crystalline form known as stishovite -- a structure believed to exist in the deep Earth. Others have argued that because of the fast timescale of the shock the material will instead adopt a dense, glassy structure.

Tracy and her team were able to demonstrate that counter to expectations, when subjected to a dynamic shock of greater than 300,000 times normal atmospheric pressure, quartz undergoes a transition to a novel disordered crystalline phase, whose structure is intermediate between fully crystalline stishovite and a fully disordered glass. However, the new structure cannot last once the burst of intense pressure has subsided.

"Dynamic compression experiments allowed us to put this longstanding debate to bed," Tracy concluded. "What's more, impact events are an important part of understanding planetary formation and evolution and continued investigations can reveal new information about these processes."

This research was supported by the Defense Threat Reduction Agency and the NSF. Washington State University (WSU) provided experimental support through awards from the U.S. Department of Energy (DOE)/National Nuclear Security Agency (NNSA).

Read more at Science Daily