Butterfly-inspired films create vibrant colors while passively cooling objects

On a hot summer day, white clothing feels cooler than other colors due to reflecting -- not absorbing -- sunlight. Other colors like blue or black, will undergo a heating effect as they absorb light. To circumvent this heating effect in colored cooling films, researchers drew inspiration from nanostructures in butterfly wings.

The new films, which don't absorb any light, could be used on the outside of buildings, vehicles and equipment to reduce the energy needed for cooling while preserving vivid color properties.

"In buildings, large amounts of energy are used for cooling and ventilation, and running the air conditioner in electric cars can reduce the driving range by more than half," said research team leader Wanlin Wang from Shenzhen University in China. "Our cooling films could help advance energy sustainability and carbon neutrality."

In Optica, Optica Publishing Group's journal for high-impact research, the researchers show that the films they developed lower the temperature of colorful objects to about 2 °C below the ambient temperature. They also found that when left outside all day, the blue version of the films was approximately 26°C cooler than traditional blue car paint. This represents an annual energy savings of approximately 1377 MJ/m2 per year.

"With our new films, excellent cooling performance can be achieved, no matter the desired color, saturation or brightness," said Wang. "They could even be used on textiles to create clothes of any color that are comfortable in hot temperatures."

Inspired by nature

A car with blue paint appears blue because it absorbs yellow light and reflects blue light. The large amount of light that is absorbed heats the car. Morpho butterflies, however, produce their highly saturated blue color based on the nanostructure of their wings. The design of the cooling nanofilm mimics these structures to produce vibrant colors that don't absorb light like traditional paint.

To create their Morpho-inspired nanofilms, the researchers placed a disordered material (rough frosted glass) under a multilayer material made of titanium dioxide and aluminum dioxide. They then placed this structure on a silver layer that reflects all light, thus preventing the absorption of solar radiation and the heating associated with that absorption.

The film's color is determined by how components within its multilayered structure reflect light. To create blue, for example, the multilayer material is designed to reflect yellow light in a very narrow range of angles while the disordered structure diffuses the blue light across a broad area.

Although this type of passive photonic thermal management has been accomplished before, it has only been used with white or clear objects because it is difficult to maintain a wide viewing angle and high color saturation.

Passive cooling of colorful objects

"Thanks to the layered structure we developed, we were able to extend the passive cooling method from colorless objects to colorful ones while preserving color performance," said Wang. "In other words, our blue film looks blue across a large range of viewing angles and doesn't heat up because it reflects all the light. In addition, high saturation and brightness can be achieved by optimizing the structure."

To test the new technology, the researchers created blue, yellow and colorless films, which they placed outdoors at Shenzhen University, on surfaces such as roofs, cars, cloth and cell phones, from 9 a.m. to 4 p.m. in both winter and summer. Using thermocouple sensors and infrared cameras to measure temperature, they found that the cooling films were more than about 15 ? cooler than the surfaces they were placed on in the winter and about 35 ? cooler in the summer.

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Low volcanic temperature ushered in global cooling and the thriving of dinosaurs

Researchers in Japan, Sweden, and the US have unearthed evidence that low volcanic temperatures led to the fourth mass extinction, enabling dinosaurs to flourish during the Jurassic period.

Large volcanic eruptions create climatic fluctuations, ushering in evolutionary changes. Yet it is the volcanic temperature of the eruption that determines whether the climate cools or warms.

Since the emergence of early animals, five mass extinctions have taken place. The fourth mass extinction occurred at the end of the Triassic Period -- roughly 201 million years ago. This mass extinction saw many marine and land animals go extinct, especially large-body, crocodilian-line reptiles known as pseudosuchia. Approximately 60-70% of animal species disappeared. As a result, small bodied dinosaurs were able to grow and prosper.

Scientists think the fourth mass extinction was triggered by the eruptions in the Central Atlantic Magmatic Province -- one of the largest regions of volcanic rock. But the correlation between the eruption and mass extinction has not yet been clarified.

Using analysis of sedimentary organic molecules and a heating experiment, current professor emeritus at Tohoku University, Kunio Kaiho and his team demonstrated how low temperature magma slowly heated sedimentary rocks, causing high sulfur dioxide (SO2) and low carbon dioxide emissions (CO2).

The SO2 gas was distributed throughout the stratosphere, converting to sulfuric acid aerosols. The instantaneous increase of global albedo caused short-term cooling, which could have contributed to the mass extinction.

Kaiho and his team took marine sedimentary rock samples from Austria and the United Kingdom and analyzed the organic molecules and mercury (Hg) in them. They found four discrete benzo[e]pyrene + benzo[ghi]perylene + coronene -Hg enrichments.

The discovery of low coronene in the first enrichment was particularly revealing. The second, third, and fifth mass extinction had high coronene concentrations. A low concentration indicates that low temperature heating caused high SO2 release and global cooling.

"We believe the extinction was the product of large volcanic eruptions because the benzo[e]pyrene + benzo[ghi]perylene + coronene anomaly could only be seen around the time frame of the mass extinctions," said Kaiho.

Read more at Science Daily