Biomolecules from formaldehyde on ancient Mars

Organic materials discovered on Mars may have originated from atmospheric formaldehyde, according to new research, marking a step forward in our understanding of the possibility of past life on the Red Planet.

Scientists from Tohoku University have investigated whether the early atmospheric conditions on Mars had the potential to foster the formation of biomolecules -- organic compounds essential for biological processes.

Their findings, published in Scientific Reports, offer intriguing insights into the plausibility of Mars harboring life in its distant past.

Today, Mars presents a harsh environment characterized by dryness and extreme cold, but geological evidence hints at a more hospitable past.

About 3.8-3.6 billion years ago, the planet probably had a temperate climate, sustained by the warming properties of gases like hydrogen.

In such an environment, Mars may have had liquid water, a key ingredient for life as we know it.

The researchers investigated whether formaldehyde could have formed in the early Martian environment.

Formaldehyde is a simple organic compound that plays a crucial role as a precursor for the formation of vital biomolecules through purely chemical or physical processes.

These biomolecules, like amino acids and sugars, serve as the fundamental building blocks for proteins and RNA, essential components of life.

Using an advanced computer model, the team simulated the potential atmospheric composition of early Mars to explore the potential for formaldehyde production.

The model was built with the assumption that the atmosphere was rich in carbon dioxide, hydrogen, and carbon monoxide.

Their simulations suggest that the ancient Martian atmosphere could have provided a continuous supply of formaldehyde which would have potentially led to the creation of various organic compounds.

This raises the intriguing possibility that the organic materials detected on the Martian surface could have originated from atmospheric sources, particularly during the planet's two earliest geological periods.

"Our research provides crucial insights into the chemical processes that may have occurred on ancient Mars, offering valuable clues to the possibility of past life on the planet," says Shungo Koyama, lead author of the study.

By revealing that there were conditions favorable for the formation of bio molecules, the research broadens our understanding of the planet's ancient capacity to sustain life.

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Little groundwater recharge in ancient Mars aquifer, according to new models

Mars was once a wet world. The geological record of the Red Planet shows evidence for water flowing on the surface -- from river deltas to valleys carved by massive flash floods.

But a new study shows that no matter how much rainfall fell on the surface of ancient Mars, very little of it seeped into an aquifer in the planet's southern highlands.

A graduate student at The University of Texas at Austin made the discovery by modeling groundwater recharge dynamics for the aquifer using a range of methods -- from computer models to simple back-of-the-envelope calculations.

No matter the degree of complexity, the results converged on the same answer -- a miniscule .03 millimeters of groundwater recharge per year on average.

That means that wherever rain fell in the model, only an average of .03 millimeters per year could have entered the aquifer and still produced the landforms remaining on the planet today.

For comparison, the annual rate of groundwater recharge for the Trinity and Edwards-Trinity Plateau aquifers that provide water to San Antonio generally ranges from 2.5 to 50 millimeters per year, or about 80 to 1,600 times the Martian aquifer recharge rate calculated by the researchers.

There are a variety of potential reasons for such low groundwater flow rates, said lead author Eric Hiatt, a doctoral student at the Jackson School of Geosciences.

When it rained, the water may have mostly washed across the Martian landscape as runoff.

Or it may have just not rained very much at all.

These findings can help scientists constrain the climatic conditions capable of producing rainfall on early Mars.

They also suggest a very different water regime on the Red Planet than what exists on Earth today.

"The fact that the groundwater isn't as big of a process could mean that other things are," Hiatt said.

"It might magnify the importance of runoff, or it could mean that it just didn't rain as much on Mars. But it's just fundamentally different from how we think about [water] on Earth."

The results were published in the journal Icarus. The paper's co-authors are Mohammad Afzal Shadab, a doctoral student at the Jackson School and faculty members Sean Gulick, Timothy Goudge and Marc Hesse.

The models used in the study work by simulating groundwater flow in a "steady state" environment where inflow and outflow of water into the aquifer is balanced.

Scientists then changed the parameters affecting the flow -- for example, where rain falls or the average porosity of the rock -- and observed what other variables would have to change to maintain the steady state and how plausible those charges are.

While other researchers have simulated groundwater flow on Mars using similar techniques, this model is the first to incorporate the influence of the oceans that existed on the surface of Mars more than three billion years ago in the Hellas, Argyre, and Borealis basins.

The study also incorporates modern topographical data collected by satellites.

The modern landscape, Hiatt said, still preserves one of the planet's oldest and most influential topographical features -- an extreme difference in elevation between the northern hemisphere -- the lowlands -- and the southern hemisphere -- the highlands -- known as the "great dichotomy." The dichotomy preserves signs of past groundwater upwelling in which groundwater rose up from the aquifer to the surface.

The researchers used geological markers of these past upwelling events to evaluate different model outputs.

Across different models, the researchers found the mean groundwater recharge rate of .03 millimeters per year to match most closely with what's known about the geologic record.

The research isn't just about understanding the Red Planet's past.

It has implications for future Mars exploration too. Understanding groundwater flow can help inform where to find water today, Hiatt said.

Whether you're looking for signs of ancient life, trying to sustain human explorers, or making rocket fuel to get back home to Earth, it's essential to know where the water would most likely be.

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Researchers complete first real-world study of Martian helicopter dust dynamics

Mars is a dusty planet. From tiny dust devils to vast storms that shroud the planet, dust is a constant challenge for research missions. That was especially true for Ingenuity, the rotorcraft that since February 2021 has been exploring Mars alongside NASA's Perseverance rover. Now, researchers at Stevens Institute of Technology, the Space Science Institute, and the Jet Propulsion Laboratory have completed the first real-world study of Martian dust dynamics based on Ingenuity's historic first flights on the Red Planet, paving the way for future extraterrestrial rotorcraft missions.

The work, reported in the December 2022 issue of Journal of Geophysical Research: Planets, could support NASA's Mars Sample Return Program, which will retrieve samples collected by Perseverance, or the Dragonfly mission that will set course for Titan, Saturn's largest moon, in 2027.

"There's a reason that helicopter pilots on Earth prefer to land on helipads," said Jason Rabinovitch, a co-author and assistant professor at Stevens. "When a helicopter lands in the desert, its downdraft can stir up enough dust to cause a zero-visibility 'brownout' -- and Mars is effectively one big desert."

Rabinovitch has been working on the Ingenuity program since 2014, joining the Jet Propulsion Laboratory soon after the concept was first pitched to NASA and creating the first theoretical models of helicopter dust lifting in the dusty Martian environments. At Stevens, Rabinovitch continues to work with JPL and investigates plume-surface interactions during powered descent of a spacecraft. He also models supersonic parachute inflation and geophysical phenomena, such as plumes on Enceladus.

Studying dust dynamics on another planet isn't easy, explained Rabinovitch. "Space is a data-poor environment. It's hard to send videos and images back to Earth, so we have to work with what we can get."

To overcome that challenge, Rabinovitch and colleagues at JPL used advanced image-processing techniques to extract information from six helicopter flights, all low-resolution videos captured by Perseverance. By identifying tiny variations between video frames, and the light intensity of individual pixels, the researchers were able to calculate both the size and the total mass of dust clouds kicked up as Ingenuity took off, hovered, maneuvered, and landed.

The results were within striking distance of Rabinovitch's engineering models -- itself a remarkable achievement, given the limited information available to the team way back in 2014, when Rabinovitch and his colleagues were writing back-of-the-envelope calculations intended to support the original design of Ingenuity.

The research shows that, as predicted, dust is a significant consideration for extra-terrestrial rotorcraft, with Ingenuity estimated to have kicked up about a thousandth of its own mass (four pounds) in dust each time it flew. That's many times more dust than would be generated by an equivalent helicopter on Earth, though Rabinovitch cautions that it's tricky to draw direct comparisons.

"It was exciting to see the Mastcam-Z video from Perseverance, which was taken for engineering reasons, ended up showing Ingenuity lifting so much dust from the surface that it opened a new line of research," said Mark Lemmon, senior research scientist at the Space Science Institute Mars Science Laboratory and first author of the study.

"When you think about dust on Mars, you have to consider not just the lower gravity, but also the effects of air pressure, temperature, air density -- there's a lot we don't yet fully understand," Rabinovich said. Still, he added, that's what makes studying Ingenuity's dust clouds so exciting.

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Martian meteorite contains large diversity of organic compounds

The Martian meteorite Tissint contains a huge diversity of organic compounds, found an international team of researchers led by Technical University of Munich and Helmholtz Munich's Philippe Schmitt-Kopplin and including Carnegie's Andrew Steele. Their work is published in Science Advances.

Tissint, which crash landed in Morocco more than 11 years ago, is one of only five Martian meteorites that have been observed as they fell to Earth. Pieces of it were found scattered around the desert about 30 miles from the town after which it is named.

This sample of Martian rock was formed hundreds of millions of years ago on our next-door planetary neighbor and was launched into space by a violent event. Unraveling the origin stories of the Tissint meteorite's organic compounds can help scientists understand whether the Red Planet ever hosted life, as well as Earth's geologic history.

"Mars and Earth share many aspects of their evolution," said lead author Schmitt-Kopplin. "And while life arose and thrived on our home planet, the question of whether it ever existed on Mars is a very hot research topic that requires deeper knowledge of our neighboring planet's water, organic molecules, and reactive surfaces."

Organic molecules contain carbon, hydrogen, oxygen, nitrogen, sulfur, and sometimes other elements. Organic compounds are commonly associated with life, although previous Martian meteorite research demonstrated that they can be created by non-biological processes, referred to as abiotic organic chemistry.

"Understanding the processes and sequence of events that shaped this rich organic bounty will reveal new details about Mars' habitability and potentially about the reactions that could lead to the formation of life," added Steele, who has done extensive research on organic material in Martian meteorites, including Tissint, and is a member of both the Perseverance and Curiosity rovers' science teams.

The researchers were able to thoroughly analyze the meteorite's organic inventory, revealing a link between the type and diversity of organic molecules and specific mineralogy. Their efforts resulted in the most comprehensive catalog ever made of the diversity of organic compounds found in a Martian meteorite or in a sample collected and analyzed by a rover. This work uncovered details about how the processes occurring in Mars' mantle and crust evolved, especially with regard to abiotic organics that formed from water-rock interactions.

Of particular interest was the abundance of organic magnesium compounds, a suite of organic molecules not previously seen on Mars, which offer new insights about the high-pressure, high-temperature geochemistry that shaped the Red Planet's deep interior and indicate a connection between its carbon cycle and its mineral evolution.

The researchers say that samples returned from Mars by future missions should provide an unprecedented amount of information about the formation, stability and dynamics of organic compounds in real Martian environments.

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