Massive 2022 eruption reduced ozone layer levels

When the Hunga Tonga-Hunga Ha'apai volcano erupted on January 15, 2022 in the South Pacific, it produced a shock wave felt around the world and triggered tsunamis in Tonga, Fiji, New Zealand, Japan, Chile, Peru and the United States. It also changed the chemistry and dynamics of the stratosphere in the year following the eruption, leading to unprecedented losses in the ozone layer of up to 7% over large areas of the Southern Hemisphere, according to a recent study published in the Proceedings of the National Academy of Sciences (PNAS) from the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS) and the University of Maryland.

Driving those atmospheric changes, according to the research, was the sheer amount of water vapor injected into the stratosphere by the undersea volcano.

The location of the stratosphere is approximately 8 -- 30 miles above Earth's surface and is where the protective ozone layer resides.

"The Hunga Tonga-Hunga Ha'apai eruption was truly extraordinary in that it injected about 300 billion pounds of water into the normally dry stratosphere, which is just an absolutely incredible amount of water from a single event," said David Wilmouth, a project scientist at SEAS and first author of the paper.

"This eruption put us in uncharted territory," said Ross Salawitch, professor at the University of Maryland's Earth System Science Interdisciplinary Center and co-author of the study.

"We've never seen, in the history of satellite records, this much water vapor injected into the atmosphere and our paper is the first that looks at the downstream consequences over broad regions of both hemispheres in the months following the eruption using satellite data and a global model."

The Hunga Tonga-Hunga Ha'apai eruption was the largest explosion ever recorded in the atmosphere.

The eruption hurled aerosols and gases deep into the stratosphere.

Some material reached the lower mesosphere, more than 30 miles above the Earth's surface, altitudes never recorded from a volcanic eruption.

Previous studies found that the eruption increased water vapor in the stratosphere by 10% worldwide, with even higher concentrations in some areas of the Southern Hemisphere.

Wilmouth, Salawitch and the rest of the research team used data from the Microwave Limb Sounder (MLS) aboard the NASA Aura satellite, to track not only how that water vapor moved across the globe but also monitor temperature and levels of chlorine monoxide (ClO), ozone (O3), nitric acid (HNO3), and hydrogen chloride (HCl) in the stratosphere for the year following the eruption.

They then compared those measurements to data collected by MLS from 2005 to 2021 prior to the eruption.

The team found that the injection of water vapor and sulfur dioxide (SO2) changed both the chemistry and the dynamics of the stratosphere.

In terms of chemistry, the SO2 led to an increase of sulfate aerosols, which provided new surfaces for chemical reactions to occur.

"Certain reactions that might not happen at all or only happen slowly can happen faster if there are aerosols available on which those reactions can take place," said Wilmouth.

"The injection of SO2 from the volcano allowed sulfate aerosols to form and the presence of water vapor led to the additional production of sulfate aerosols."

The increased sulfate aerosols and water vapor kicked off a chain of events in the complex atmospheric chemistry that led to widespread changes in the concentrations of a number of compounds, including ozone.

The extra water vapor also had a cooling effect in the stratosphere, leading to a change in circulation, which drove decreases in ozone in the southern hemisphere and an increase of ozone over the tropics.

The researchers found that the peak decrease in ozone occurred in October, nine months after the eruption.

"We had this enormous increase in water vapor in the stratosphere with modest increases in sulfate that set off a series of events that led to significant changes in temperature and circulation, ClO, HNO3, HCl, O3, and other gases," Wilmouth said.

Next, the researchers hope to continue the study by following the impact of the volcano into 2023 and beyond as the water vapor moves from the tropics and midlatitudes to the Southern Hemisphere pole, where it has the potential to amplify ozone losses in the Antarctic.

The water vapor is expected to stay elevated in the stratosphere for a period of several years.

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Arctic stratospheric ozone levels hit record low in March

Ozone levels above the Arctic reached a record low for March, NASA researchers report. An analysis of satellite observations show that ozone levels reached their lowest point on March 12 at 205 Dobson units.

While such low levels are rare, they are not unprecedented. Similar low ozone levels occurred in the upper atmosphere, or stratosphere, in 1997 and 2011. In comparison, the lowest March ozone value observed in the Arctic is usually around 240 Dobson units.

"This year's low Arctic ozone happens about once per decade," said Paul Newman, chief scientist for Earth Sciences at NASA's Goddard Space Flight Center in Greenbelt, Maryland. "For the overall health of the ozone layer, this is concerning since Arctic ozone levels are typically high during March and April."

Ozone is a highly reactive molecule comprised of three oxygen atoms that occurs naturally in small amounts. The stratospheric ozone layer, roughly 7 to 25 miles above Earth's surface, is a sunscreen, absorbing harmful ultraviolet radiation that can damage plants and animals and affecting people by causing cataracts, skin cancer and suppressed immune systems.

The March Arctic ozone depletion was caused by a combination of factors that arose due to unusually weak upper atmospheric "wave" events from December through March. These waves drive movements of air through the upper atmosphere akin to weather systems that we experience in the lower atmosphere, but much bigger in scale.

In a typical year, these waves travel upward from the mid-latitude lower atmosphere to disrupt the circumpolar winds that swirl around the Arctic. When they disrupt the polar winds, they do two things. First, they bring with them ozone from other parts of the stratosphere, replenishing the reservoir over the Arctic.

"Think of it like having a red-paint dollop, low ozone over the North Pole, in a white bucket of paint," Newman said. "The waves stir the white paint, higher amounts of ozone in the mid-latitudes, with the red paint or low ozone contained by the strong jet stream circling around the pole."

The mixing has a second effect, which is to warm the Arctic air. The warmer temperatures then make conditions unfavorable for the formation of polar stratospheric clouds. These clouds enable the release of chlorine for ozone-depleting reactions. Ozone depleting chlorine and bromine come from chlorofluorocarbons and halons, the chemically active forms of chlorine and bromine derived from human-made compounds that are now banned by the Montreal Protocol. The mixing shuts down this chlorine and bromine driven ozone depletion.

In December 2019 and January through March of 2020, the stratospheric wave events were weak and did not disrupt the polar winds. The winds thus acted like a barrier, preventing ozone from other parts of the atmosphere from replenishing the low ozone levels over the Arctic. In addition, the stratosphere remained cold, leading to the formation of polar stratospheric clouds which allowed chemical reactions to release reactive forms of chlorine and cause ozone depletion.

"We don't know what caused the wave dynamics to be weak this year," Newman said. "But we do know that if we hadn't stopped putting chlorofluorocarbons into the atmosphere because of the Montreal Protocol, the Arctic depletion this year would have been much worse."

Since 2000, levels of chlorofluorocarbons and other human-made ozone-depleting substances have measurably decreased in the atmosphere and continue to do so. Chlorofluorocarbons are long-lived compounds that take decades to break down, and scientists expect stratospheric ozone levels to recover to 1980 levels by mid-century.

NASA researchers prefer the term "depletion" over the Arctic, since despite the ozone layer's record low this year, the ozone loss is still much less than the annual ozone "hole" that occurs over Antarctica in September and October during Southern Hemisphere spring. For comparison, ozone levels over Antarctica typically drop to about 120 Dobson units.

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