Astrophysicists crack the case of 'disappearing' Sulphur in planetary nebulae

Two astrophysicists from the Laboratory for Space Research (LSR) at The University of Hong Kong (HKU) have finally solved a 20-year-old astrophysical puzzle concerning the lower-than-expected amounts of the element Sulphur found in Planetary Nebulae (PNe) in comparison to expectations and measurements of other elements and other types of astrophysical objects.

The expected levels of Sulphur have long appeared to be "missing in action." However, they have now finally reported for duty after hiding in plain sight, as a result of leveraging highly accurate and reliable data.

The team has recently reported their findings in Astrophysical Journal Letters.

Background

PNe are the short-lived glowing, ejected, gaseous shrouds of dying stars that have long fascinated and enthused professional and amateur astronomers alike with their colourful and varied shapes.

PNe live for only a few tens of thousands of years compared to their host stars, which can take billions of years before they pass through the PN phase on the way to becoming "white dwarfs." Consequently, PNe provide an almost instantaneous snapshot of stellar death throes.

They are a vital, scientific window into late-stage stellar evolution as their rich emission line spectra enable detailed studies of their chemical compositions.

The Enigmatic Sulphur Anomaly

Past studies showed that PNe optical spectra appeared to have a varying deficit of the element Sulphur.

This deficit was difficult to explain because Sulphur, known as an "α element," should be produced in lockstep with other elements like oxygen, neon, argon and chlorine in more massive stars.

As a result, its cosmic abundance should also be directly proportional.

Surprisingly, while strong correlations between Sulphur and Oxygen abundances have been observed in H II regions (Hydrogen ionised region) and blue compact galaxies, PNe originating from low- to intermediate-mass stars consistently exhibit lower Sulfur levels, giving rise to the so-called mysterious "sulfur anomaly" that has perplexed and annoyed astronomers for decades.

Our Work Solving the Mystery

Ms Shuyu TAN, a graduate of HKU MPhil in Physics and Research Assistant at HKU LSR, along with her supervisor Professor Quentin PARKER, the Director of LSR, utilised an unprecedented sample of exceptional high signal to noise (S/N) optical spectra for approximately 130 PNe located in the centre of our Galaxy.

This exceptional dataset had minimal background noise, allowing for a clear and detailed examination of the spectral features, helping the team effectively tackle and solve the mystery.

These PNe were observed using the world-leading European Southern Observatory (ESO) 8m Very Large Telescope in Chile.

It turns out the anomaly was essentially a result of poor data quality for Sulphur emission lines in PNe spectra.

It was found that using Oxygen as the base metallicity comparator to other elements was not accurate, and instead, Argon demonstrated a stronger correlation with Oxygen for Sulphur and has been suggested as a more reliable indicator of metallicity and a suitable comparison element.

So, when a large, carefully selected sample of PNe are spectroscopically observed at high S/N on a large telescope, not only did the data reveal a strong "lock-step" behaviour or Sulphur in PNe for the first time, as seen and expected for other types of astrophysical objects, but the anomaly itself effectively went away.

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Does ice in the Universe contain the molecules making up the building blocks of life in planetary systems?

The James Webb Space Telescope -- the most precise telescope ever built -- was decisive in discovering the frozen forms of a long series of molecules, such as carbon dioxide, ammonia, methane, methanol and even more complex molecules, frozen out as ices on the surface of small dust grains.

The dust grains grow in size when being a part of the discs of gas and dust forming around young stars. This means that the researchers could study many of the molecules going into the forming of new exoplanets.

Researchers at the Niels Bohr Institute, University of Copenhagen, combined the discoveries from JWST with data from Atacama Large Millimeter Array (ALMA), making observations in other wavelengths than JWST and researchers from Aarhus University contributed with the necessary investigations in the laboratory.

"With the application of observations, e.g. from ALMA, it is possible for us to directly observe the dust grains themselves, and it is also possible to see the same molecules as in the gas observed in the ice" Lars Kristensen, associate Professor at the Niels Bohr Institute (NBI), explains.

"Using the combined data set gives us a unique insight into the complex interactions between gas, ice and dust in areas where stars and planets form" according to Jes Jørgensen, Professor at NBI.

"This way we can map the location of the molecules in the area both before and after they have been frozen out onto the dust grains and we can follow their path from the cold molecular cloud to the emerging planetary systems around young stars."

The content of ice in the molecular cloud was a decisive discovery

The ices were detected and measured by studying how starlight from beyond the molecular cloud was absorbed by icy molecules at specific infrared wavelengths visible to Webb.

This process leaves behind chemical fingerprints known as absorption spectra which can be compared with laboratory data to identify which ices are present in the molecular cloud.

In this study, the team targeted ices buried in a particularly cold, dense and difficult to investigate region of the Chamaeleon I molecular cloud, a region approximately 600 light-years from Earth which is currently in the process of forming dozens of young stars.

Along with star forming comes planet forming and the perspective for the researchers in the IceAge collaboration is basically to identify the role the ice plays in gathering the molecules necessary to form life.

"This study confirms that interstellar grains of dust are catalysts for the forming of complex molecules in the very diffuse gas in these clouds, something we see in the lab as well," Sergio Ioppolo explains, associate professor at Aarhus University, contributing with some of the experiments in the lab that were compared with the observations.

The sensitivity of JWST was an absolutely necessary precondition for the discovery

"We simply couldn't have observed these ices without Webb," elaborated Klaus Pontoppidan, JWST project scientist at the Space Telescope Science Institute, Baltimore, USA, who was involved in this research.

"The ices show up as dips against a continuum of background starlight. In regions that are this cold and dense, much of the light from the background star is blocked and Webb's exquisite sensitivity was necessary to detect the starlight and therefore identify the ices in the molecular cloud."

The IceAge team has already planned more observations with both Webb and other telescopes.

"These observations together with further laboratory studies will tell us which mixture of ices -- and therefore which elements -- can eventually be delivered to the surfaces of terrestrial exoplanets or incorporated into the atmospheres of giant gas or ice planets.

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Scientists map sulfur residue on Jupiter's icy moon Europa

A Southwest Research Institute-led team used the Hubble Space Telescope to observe Jupiter's moon, Europa, at ultraviolet wavelengths, filling in a "gap" in the various wavelengths used to observe this icy water world. The team's near-global UV maps show concentrations of sulfur dioxide on Europa's trailing side.

SwRI will further these studies using the Europa Ultraviolet Spectrograph (Europa-UVS), which will observe Jupiter's fourth largest moon from aboard NASA's Europa Clipper, scheduled to launch in 2024. Scientists are almost certain that hidden beneath Europa's icy surface is a saltwater ocean containing nearly twice as much water as is in all of Earth's oceans. This moon may be the most promising place in our solar system suitable for some form of life beyond Earth.

"Europa's relatively young surface is primarily composed of water ice, although other materials have been detected across its surface," said Dr. Tracy Becker, lead author of a paper describing these UV observations. "Determining whether these other materials are native to Europa is important for understanding Europa's formation and subsequent evolution."

Assessing the surface material can provide insights into the composition of the subsurface ocean. SwRI's dataset is the first to produce a near-global map of sulfur dioxide that correlates with large-scale darker regions in both the visible and the ultraviolet wavelengths.

"The results were not surprising, but we did get much better coverage and resolution than previous observations," said SwRI's Dr. Philippa Molyneux, a co-author of the paper. "Most of the sulfur dioxide is seen on the 'trailing' hemisphere of Europa. It's likely concentrated there because Jupiter's co-rotating magnetic field traps sulfur particles spewing from Io's volcanoes and slams them against the backside of Europa."

Io is another of Jupiter's largest moons but, in contrast, is considered the most volcanic body in the solar system. Jupiter's magnetic field can cause chemical reactions between the water ice and the sulfur, creating sulfur dioxide on Europa's surface.

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No signs (yet) of life on Venus

The unusual behaviour of sulphur in Venus' atmosphere cannot be explained by an 'aerial' form of extra-terrestrial life, according to a new study.

Researchers from the University of Cambridge used a combination of biochemistry and atmospheric chemistry to test the 'life in the clouds' hypothesis, which astronomers have speculated about for decades, and found that life cannot explain the composition of the Venusian atmosphere.

Any life form in sufficient abundance is expected to leave chemical fingerprints on a planet's atmosphere as it consumes food and expels waste. However, the Cambridge researchers found no evidence of these fingerprints on Venus.

Even if Venus is devoid of life, the researchers say their results, reported in the journal Nature Communications, could be useful for studying the atmospheres of similar planets throughout the galaxy, and the eventual detection of life outside our Solar System.

"We've spent the past two years trying to explain the weird sulphur chemistry we see in the clouds of Venus," said co-author Dr Paul Rimmer from Cambridge's Department of Earth Sciences. "Life is pretty good at weird chemistry, so we've been studying whether there's a way to make life a potential explanation for what we see."

The researchers used a combination of atmospheric and biochemical models to study the chemical reactions that are expected to occur, given the known sources of chemical energy in Venus's atmosphere.

"We looked at the sulphur-based 'food' available in the Venusian atmosphere -- it's not anything you or I would want to eat, but it is the main available energy source," said Sean Jordan from Cambridge's Institute of Astronomy, the paper's first author. "If that food is being consumed by life, we should see evidence of that through specific chemicals being lost and gained in the atmosphere."

The models looked at a particular feature of the Venusian atmosphere -- the abundance of sulphur dioxide (SO2). On Earth, most SO2 in the atmosphere comes from volcanic emissions. On Venus, there are high levels of SO2 lower in the clouds, but it somehow gets 'sucked out' of the atmosphere at higher altitudes.

"If life is present, it must be affecting the atmospheric chemistry," said co-author Dr Oliver Shorttle from Cambridge's Department of Earth Sciences and Institute of Astronomy. "Could life be the reason that SO2 levels on Venus get reduced so much?"

The models, developed by Jordan, include a list of metabolic reactions that the life forms would carry out in order to get their 'food', and the waste by-products. The researchers ran the model to see if the reduction in SO2 levels could be explained by these metabolic reactions.

They found that the metabolic reactions can result in a drop in SO2 levels, but only by producing other molecules in very large amounts that aren't seen. The results set a hard limit on how much life could exist on Venus without blowing apart our understanding of how chemical reactions work in planetary atmospheres.

"If life was responsible for the SO2 levels we see on Venus, it would also break everything we know about Venus's atmospheric chemistry," said Jordan. "We wanted life to be a potential explanation, but when we ran the models, it isn't a viable solution. But if life isn't responsible for what we see on Venus, it's still a problem to be solved -- there's lots of strange chemistry to follow up on."

Although there's no evidence of sulphur-eating life hiding in the clouds of Venus, the researchers say their method of analysing atmospheric signatures will be valuable when JWST, the successor to the Hubble Telescope, begins returning images of other planetary systems later this year. Some of the sulphur molecules in the current study are easy to see with JWST, so learning more about the chemical behaviour of our next-door neighbour could help scientists figure out similar planets across the galaxy.

"To understand why some planets are alive, we need to understand why other planets are dead," said Shorttle. "If life somehow managed to sneak into the Venusian clouds, it would totally change how we search for chemical signs of life on other planets."

"Even if 'our' Venus is dead, it's possible that Venus-like planets in other systems could host life," said Rimmer, who is also affiliated with Cambridge's Cavendish Laboratory. "We can take what we've learned here and apply it to exoplanetary systems -- this is just the beginning."

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