Microrobots clean up radioactive waste

According to some experts, nuclear power holds great promise for meeting the world's growing energy demands without generating greenhouse gases. But scientists need to find a way to remove radioactive isotopes, both from wastewater generated by nuclear power plants and from the environment in case of a spill. Now, researchers reporting in ACS Nano have developed tiny, self-propelled robots that remove radioactive uranium from simulated wastewater.

The accidental release of radioactive waste, such as what occurred in the Chernobyl and Fukushima nuclear plant disasters, poses large threats to the environment, humans and wildlife. Scientists have developed materials to capture, separate, remove and recover radioactive uranium from water, but the materials have limitations. One of the most promising recent approaches is the use of metal-organic frameworks (MOFs) -- compounds that can trap specific substances, including radioactive uranium, within their porous structures. Martin Pumera and colleagues wanted to add a micromotor to a rod-shaped MOF called ZIF-8 to see if it could quickly clean up radioactive waste.

To make their self-propelled microrobots, the researchers designed ZIF-8 rods with diameters about 1/15 that of a human hair. The researchers added iron atoms and iron oxide nanoparticles to stabilize the structures and make them magnetic, respectively. Catalytic platinum nanoparticles placed at one end of each rod converted hydrogen peroxide "fuel" in the water into oxygen bubbles, which propelled the microrobots at a speed of about 60 times their own length per second. In simulated radioactive wastewater, the microrobots removed 96% of the uranium in an hour. The team collected the uranium-loaded rods with a magnet and stripped off the uranium, allowing the tiny robots to be recycled. The self-propelled microrobots could someday help in the management and remediation of radioactive waste, the researchers say.

From Science Daily

Mysterious release of radioactive material uncovered

Radiation symbol.

It was the most serious release of radioactive material since Fukushima 2011, but the public took little notice of it: In September 2017, a slightly radioactive cloud moved across Europe. Now, a study has been published, analyzing more than 1300 measurements from all over Europe and other regions of the world to find out the cause of this incident. The result: it was not a reactor accident, but an accident in a nuclear reprocessing plant. The exact origin of the radioactivity is difficult to determine, but the data suggests a release site in the southern Urals. This is where the Russian nuclear facility Majak is located. The incident never caused any kind of health risks for the European population.

Among the 70 experts from all over Europe who contributed data and expertise to the current study are Dieter Hainz and Dr. Paul Saey from the Institute of Atomic and Subatomic Physics at TU Wien (Vienna). The data was evaluated by Prof. Georg Steinhauser from the University of Hanover (who is closely associated with the Atomic Institute) together with Dr. Olivier Masson from the Institut de Radioprotection et de Sûreté Nucléaire (IRSN) in France. The team has now published the results of the study in the journal Proceedings of the National Academy of Sciences (PNAS).

Unusual Ruthenium Release

"We measured radioactive ruthenium-106," says Georg Steinhauser. "The measurements indicate the largest singular release of radioactivity from a civilian reprocessing plant." In autumn of 2017, a cloud of ruthenium-106 was measured in many European countries, with maximum values of 176 millibecquerels per cubic meter of air. The values were up to 100 times higher than the total concentrations measured in Europe after the Fukushima incident. The half-life of the radioactive isotope is 374 days.

This type of release is very unusual. The fact that no radioactive substances other than ruthenium were measured is a clear indication that the source must have been a nuclear reprocessing plant.

The geographic extent of the ruthenium-106 cloud was also remarkable -- it was measured in large parts of Central and Eastern Europe, Asia and the Arabian Peninsula. Ruthenium-106 was even found in the Caribbean. The data was compiled by an informal, international network of almost all European measuring stations. In total, 176 measuring stations from 29 countries were involved. In Austria, in addition to TU Wien, the AGES (Austrian Agency for Health and Food Safety) also operates such stations, including the alpine observatory at Sonnblick at 3106m above sea level.

No Health Hazard

As unusual as the release may have been, the concentration of radioactive material has not reached levels that are harmful to human health anywhere in Europe. From the analysis of the data, a total release of about 250 to 400 terabecquerel of ruthenium-106 can be derived. To date, no state has assumed responsibility for this considerable release in the fall of 2017.

The evaluation of the concentration distribution pattern and atmospheric modelling suggests a release site in the southern Urals. This is where the Russian nuclear facility Majak is located. The Russian reprocessing plant had already been the scene of the second-largest nuclear release in history in September 1957 -- after Chernobyl and even larger than Fukushima. At that time, a tank containing liquid waste from plutonium production had exploded, causing massive contamination of the area.

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