Great Salt Lake a significant source of greenhouse gas emissions

Newly announced research by Royal Ontario Museum (ROM) examining greenhouse gas emissions from the drying lake bed of Great Salt Lake, Utah, calculates that 4.1 million tons of carbon dioxide and other greenhouse gases were released in 2020. This research suggests that drying lake beds are an overlooked but potentially significant source of greenhouse gases, which may further increase due to climate change. These results were announced in the paper, "A desiccating saline lake bed is a significant source of anthropogenic greenhouse gas emissions," published in the journal One Earth.

"Human-caused desiccation of Great Salt Lake is exposing huge areas of lake bed and releasing massive quantities of greenhouse gases into the atmosphere," said Soren Brothers, who led this research and is ROM's Allan and Helaine Shiff Curator of Climate Change. "The significance of lake desiccation as a driver of climate change needs to be addressed in greater detail and considered in climate change mitigation and watershed planning."

From year to year, Great Salt Lake's water level varies, largely depending on the volume of meltwater that flows into the lake from the surrounding mountains -- from record highs in the 1980s to a record low in 2022. However, it is human-related consumption by agriculture, industry, and municipal uses, that consume ever-increasing amounts of freshwater that, over the years, has depleted the lake. Elsewhere around the world, these same competing uses for water are having a significant impact on lake levels. As iconic saline lakes such as the Aral Sea, Lake Urmia, the Caspian Sea, and Great Salt Lake dry up, they not only destroy critical habitat for biodiversity and create air quality conditions that deteriorate human health, but they also accelerate climate change as newly exposed sediments emit carbon dioxide and methane.

The research team measured carbon dioxide and methane emissions from the exposed sediments of Great Salt Lake, Utah, from April to November 2020, and compared them with aquatic emissions estimates to determine the anthropogenic greenhouse gas emissions associated with desiccation. Calculations based on this sampling indicate the lake bed emitted 4.1 million tons of greenhouse gases to the atmosphere, primarily (94%) as carbon dioxide, constituting an approximately 7% increase to Utah's human-caused greenhouse gas emissions.

Fieldwork was conducted while Soren Brothers was Assistant Professor of Limnology at Utah State University, and lead author, Melissa Cobo, was a master's student at USU. Co-author Tobias Goldhammer is a collaborating researcher at the Leibniz Institute for Freshwater Research (IGB Institute) in Berlin, Germany. Measurements of carbon dioxide and methane gases were made every two weeks from the dried-up lake bed using a portable greenhouse gas analyzer attached to a closed chamber. Seven sites at one location at the south end of the lake were visited repeatedly over the course of the year, and another three locations were sampled during an intensive three-day campaign to determine spatial variability across the lake, which at 1,700 square miles (4,400 square kilometres) is the largest saline lake in the western hemisphere.

As methane is 28 times more powerful a greenhouse gas than carbon dioxide, the global warming impact of these emissions was calculated as "carbon dioxide equivalents" to account for the greater impact of methane. Ultimately, these data indicated that greenhouse gas emissions from the dried lake bed were strongly and positively related to warm temperatures, even at sites that have been exposed for over two decades. To determine whether the lake historically would have been a significant source of greenhouse gases, the team carried out measurements of near-shore greenhouse gas emissions from the lake, as well as analyzing water chemistry collected by the team and government data sets. Together, these analyses showed that the original lake was not likely a significant source of greenhouse gases to the atmosphere, making the dried-up lake bed a novel driver of atmospheric warming.

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Surprising methane discovery in Yukon glaciers: 'Much more widespread than we thought'

Global melting is prying the lid off methane stocks, the extent of which we do not know. A young researcher from University of Copenhagen has discovered high concentrations of the powerful greenhouse gas in meltwater from three Canadian mountain glaciers, where it was not thought to exist -- adding new unknowns to the understanding of methane emissions from Earth's glaciated regions

The helicopter's rotor blades spin as its skillful pilot performs aerial acrobatics between the steep Yukon mountain sides where PhD student Sarah Elise Sapper is leading her first field expedition deep into the heart of the mountains of northwestern Canada. From the helicopter windows, her eyes fall on the jagged edge of the Donjek glacier: meltwater swirls out from beneath the ice like a whirlpool.

Soon after landing, it becomes apparent that Sarah has stumbled upon an unusual find on the first attempt. Seconds after starting up her portable methane analyzer it is clear that the air is enriched with methane and the culprit is soon found. Collecting a sample of meltwater, she measures concentrations of methane that far exceed expectations.

"We expected to find low values in the meltwater because it is believed that glacial methane emissions require larger ice masses such as vast ice sheets. But the result was quite the opposite. We measured concentrations up to 250 times higher than those in our atmosphere," explains Sarah Elise Sapper of the University of Copenhagen's Department of Geosciences and Natural Resource Management.

The field party lifted off and continued to two more mountain glaciers, Kluane and Dusty. And after measuring the methane in the meltwater of each of those two glaciers, the preliminary finding turned out to be more than an anomaly. Here too, measurements showed high methane concentrations. Somewhere beneath the ice, there are previously unknown sources of the gas.

Demonstrates possibility of widespread methane emissions

"The finding is surprising and raises several important questions within this area of research," says Associate Professor Jesper Riis Christiansen of the Department of Geosciences and Natural Resource Management.

Christiansen, the research article's co-author, believes that the finding demonstrates the possibility of methane being present beneath many of the world's glaciers, ones that have thus far been written off.

"When we suddenly see that even mountain glaciers, which are small in comparison with an ice sheet, are able to form and emit methane, it expands our basic understanding of carbon cycling in extreme environments on the planet. The formation and release of methane under ice is more comprehensive and much more widespread than we thought," he says.

Until now, the prevailing view has been that methane in meltwater could only be found in oxygen- free environments under large masses of ice like the Greenland Ice Sheet.

The researchers assume that the production of methane is biological and happens when an organic carbon source -- e.g., deposits from prehistoric marine organisms, soils, peat or forests -- is decomposed by microorganisms in the absence of oxygen, such as we know from wetlands. As such, it is surprising that the mountain glaciers emit methane.

"The meltwater from the surface of glaciers is oxygen-rich when it travels to the bottom of the ice. So we found it quite surprising that all this oxygen is used up somewhere along the way, so that oxygen-free environments form underneath these mountain glaciers. And even more surprising that it happens to such a degree, that microbes start producing methane and we can observe these high methane concentrations in the water flowing out at the glacier edges" states Sarah Elise Sapper.

"Sarah's findings change our basic understanding and send us back to the drawing board in relation to some of the key mechanisms at play," adds Jesper Riis Christiansen.

An uncertain role for the climate of the future

According to the researchers, the findings in Canada do not immediately spur an increased concern in relation to their effect on climate change. However that conclusion may be temporary.

"Methane plays a major role in warming our planet. The challenge with methane is that it is a super-potent greenhouse gas and increasing emissions will accelerate climate warming. From a global perspective, we can measure how much is emitted into the atmosphere and, roughly speaking, where the methane comes from, using the isotopes found in the atmospheric methane. And for now, the contribution of methane from ice-covered regions on our planet, including ice sheets and glaciers, isn't increasing," explains Jesper Riis Christiansen.

However, he emphasizes that the measurements cannot distinguish between methane from glaciated regions and methane from wetlands. Therefore, the numbers could be deceiving. And, the effect of melting remains unknown.

Jesper Riis Christiansen believes that the findings demand vigilance.

"The three sites Sarah measured were randomly selected due to the availability of a research station and helicopter, yet methane was found in all three. In itself, that is a good reason to better understand the area. There's too much that we don't know, and the melting glaciers expose unknown environments that have remained hidden for thousands of years. In reality, no one knows how emissions will behave," says Jesper Riis Christiansen.

He hopes that a better understanding of methane behaviour beneath glaciers will also help researchers better understand the mechanisms at play when wetlands release methane, and thereby contribute to the development of solutions to remove methane from the atmosphere through oxidation -- e.g., through the use of certain soil types.

A subglacial black box

The actual sources and locations of subglacial methane production actually remain somewhat of a mystery, hidden beneath ice masses of all sizes. Indeed, this methane can only be measured as the meltwater emerges from beneath the ice. And because it originates from large areas below the ice masses, this makes it difficult to access exactly where the production happens.

It is known to not originate from the ice itself, as concentrations both in the ice and meltwater atop it are lower than what is measured at the glacier edge. As such, the researchers believe that the methane must derive from a source beneath the ice. And the best theory, as mentioned, is that it is formed by microbes in oxygen-free pockets and then carried out with meltwater.

But this indirect knowledge of the source leaves a great deal of uncertainty about how much methane is hidden beneath the ice.

"It's a big black box under the ice -- and you could say that the meltwater is prying the lid off it. We do not know whether methane emissions from glacial areas will increase in the future with increased melting, or whether the 'lid' has already been opened to such a degree that the methane beneath the ice is actually being washed out with the meltwater," says Sarah Elise Sapper.

Methane and CO2 are different greenhouse gases

The half-life of methane in the atmosphere is 12 years.

CO2 has a much longer half-life, at roughly 1000 years.

On the other hand, methane is about 25 times more powerful as a greenhouse gas on a 100-year basis and a far more serious threat to global climate in the shorter term.

Due to greenhouse gas-driven climate change, researchers around the world are working to develop ways to capture or store CO2.

Similarly, solutions are being devised to limit the emission of -- or increase the oxidation of -- methane. Doing so requires more knowledge about how methane is formed.

Facts: Carbon circulation of methane and CO2

Biological traces from animal and plant material in the subsoil consist of carbon.

Within these environments, microorganisms have developed an ability to convert carbon into energy in a process where methane is created as a byproduct in the absence of oxygen (e.g. in beneath ice sheets or in wetlands).

However, if the methane is released into an oxygen-rich environment, it can effectively be oxidized and converted into CO2 by microbes. Wetlands play an important role in this process.

Once, in the atmosphere, methane reacts with other chemicals (hydroxyl radicals) which keep the concentrations down.

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Greenland's ice sheet is melting -- and being replaced by vegetation

An estimated 11,000 sq miles or 28,707 sq kilometres of Greenland's ice sheet and glaciers have melted over the last three decades, according to a major analysis of historic satellite records.

The total area of ice loss is equivalent to the size of Albania, and represents about 1.6 % of Greenland's total ice and glacier cover.

Where there was once ice and snow, there is now barren rock, wetlands and areas of shrub.

A team of scientists from the University of Leeds, who have tracked the changes across Greenland from the 1980s through to the 2010s, say warmer air temperatures are causing the ice to retreat, which in turn is having an impact on the temperature of the land surface, greenhouse gas emissions and the stability of the landscape.

Permafrost -- a permanently frozen layer below the Earth's surface -- is being "degraded" by the warming and in some areas, the scientists warn that it could have an impact on the infrastructure, buildings and communities that exist above it.

Their findings -- "Land cover changes across Greenland dominated by a doubling of vegetation in three decades"- are reported today (13/02) in the journal Scientific Reports.

Impact of global warming

Greenland is part of the Arctic region. It is the world's biggest island, around 836,330 sq miles in size (2.1 million sq km). Most of the land is covered by ice and glaciers and it is home to almost 57,000 people.

Since the 1970s, the region has been warming at double the global mean rate. On Greenland, average annual air temperatures between 2007 and 2012 were 3 degrees C warmer, compared with the 1979 to 2000 average.

And the researchers warn that more extreme temperatures are likely in the future.

Jonathan Carrivick, an Earth scientist based in the Faculty of Environment at Leeds and one of the authors of the study, said: "Warmer temperatures are linked to the land cover changes that we are seeing on Greenland.

"By analysing high resolution satellite images, we have been able to produce a detailed record of the land cover changes that are taking place."

Ice disappears to be replaced by bare rock and shrubs

Ice loss was concentrated around the edges of present-day glaciers but also in the north and south- west of Greenland. There were also high-levels of ice loss in localised areas in the west, mid-north-west and south-east.

Over the three decades, the amount of land with vegetation growing on it increased by 33,774 sq miles (87,475 sq km), more than doubling over the study period.

A pronounced increase in vegetation was seen across the south-west, east and north-east. The greatest increase in dense wetland vegetation occurred in the vicinity of Kangerlussuaq in the south-west and in isolated areas in the north-east.

Analysis by the researchers revealed that vegetation had increased along a latitudinal gradient between 63 degrees North and 69 degrees North and declined north of this.

Jonathan Carrivick said: "We have seen signs that the loss of ice is triggering other reactions which will result in further loss of ice and further 'greening' of Greenland, where shrinking ice exposes bare rock that is then colonised by tundra and eventually shrub.

"At the same time, water released from the melting ice is moving sediment and silt, and that eventually forms wetlands and fenlands."

Loss of ice triggers further warming

The loss of ice affects land surface temperatures because of albedo, which is the measure of how reflective a surface is.

Snow and ice are good reflectors of the sun's energy hitting the Earth's surface and this helps to keep the Earth cooler. As the ice retreats, it exposes bedrock which absorbs more solar energy, raising the temperature of the land surface.

Similarly, as ice melts it increases the quantity of water in lakes. Water absorbs more solar energy than snow and this also increases the temperature of the land surface.

Greenhouse gas emitter

The analysis shows a near quadrupling of wetlands across Greenland, particularly in the east and north-east. The wetlands are a source of methane emissions.

Writing in the paper, the researchers noted: "Expansion of vegetation and especially in wetland areas indicates but also exacerbates permafrost thaw, active layer thickening and thus emissions of greenhouse gasespreviously stored in these Arctic soils."

The researchers also developed a model to predict those areas on Greenland that are likely to see "marked and accelerated" change in the future.

Dr Michael Grimes, the lead author of the report who conducted the research as part of their PhD, added: "The expansion of vegetation, occurring in tandem with the retreat of glaciers and the ice sheet, is significantly altering the flow of sediments and nutrients into coastal waters.

"These changes are critical, particularly for the indigenous populations whose traditional subsistence hunting practices rely on the stability of these delicate ecosystems.

Read more at Science Daily

Greenhouse gas repurposed

Cutting-edge University of Auckland research converted waste carbon dioxide into a potential precursor for chemicals and carbon-free fuel.

Dr Ziyun Wang's researchers in the School of Chemical Sciences, in collaboration with researchers at Chinese institutions, have demonstrated a method for turning CO2 into formic acid, reported in the journal Nature.

In benchtop experiments, a catalyst made from waste lead-acid batteries enabled a transformation which hadn't been possible using previous catalysts.

Formic acid -- the same substance produced by ants (formica is the Latin word for ant) -- is a colourless and pungent liquid with potential as a transportation fuel, for storing electrical energy and for enabling the petrochemical industry to cut CO2 emissions.

As emissions of carbon dioxide, the primary greenhouse gas, rise each year, scientists are looking into options for the capture and storage of CO2, for repurposing CO2, and for pursuing a carbon-free economy.

Wang's group is one of the world leaders in research into CO2 electrochemical reduction (CO2RR) using acidic rather than alkaline conditions.

"This innovation opens up exciting possibilities for carbon-neutral technologies," he says.

"In the future, cars and gas stations could be using repurposed carbon dioxide."

In tests, the new method efficiently converted CO2. for more than 5,000 hours, and the researchers' calculations suggest it can be cost-effectively scaled up for industry.

The experiments used a proton exchange membrane electrolyser.

Carbon dioxide flowed into an electrochemical cell and was converted into formic acid, just like charging a battery.

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Rising sea levels could lead to more methane emitted from wetlands

As sea levels rise due to global warming, ecosystems are being altered. One small silver lining, scientists believed, was that the tidal wetlands found in estuaries might produce less methane -- a potent greenhouse gas -- as the increasing influx of seawater makes these habitats less hospitable to methane-producing microbes.

However, research from biologists at Lawrence Berkeley National Laboratory (Berkeley Lab) and UC Berkeley indicates that these assumptions aren't always true. After examining the microbial, chemical, and geological features of 11 wetland zones, the team found that a wetland region exposed to a slight amount of seawater was emitting surprisingly high levels of methane -- far more than any of the freshwater sites.

Their results, now published in mSystems, indicate that the factors governing how much greenhouse gas is stored or emitted in natural landscapes are more complex and difficult to predict than we thought.

"We looked at how many methanogens, the organisms that make methane, are present in soils at these sites and it wasn't really well correlated with the amount of methane observed," said senior author Susannah Tringe, director of Berkeley Lab's Environmental Genomics & Systems Biology Division. "And even if you look at the amount of methanotrophs, organisms that eat methane, in combination with methanogens, that doesn't seem to fully explain it."

Tringe and her colleagues took soil samples from the 11 sites and used high-throughput sequencing to analyze DNA from organisms found in the samples, including bacteria, viruses, and fungi. They examined what genes were present in the sequences and mapped them to known functions -- for example, identifying genes known to be involved in metabolizing nitrogen or genes from bacteria that use sulfate during respiration. Then they worked to model how the genetic information they found, combined with chemical factors in the soil and water, could result in the methane emissions they observed.

Across most of the sites, which ranged from freshwater to full seawater salinities, the amount of methane emitted was inversely related to the amount of salt water that was flowing in and mingling with the river water. But at one site, which had been restored in 2010 from a seasonal grassy pasture for livestock grazing back to its original wetland habitat, the team saw high methane emissions despite the moderate amount of salt water.

Seawater contains more sulfate (an ion with sulfur and oxygen) than freshwater, leading to the assumption that increased influx of seawater in these environments would lead to less methane production as the methanogens that use CO2 to make cellular energy are outcompeted by the bacteria that use sulfate instead.

"Ultimately, we found that there were significant influences from other bacterial groups like the ones that break down carbon and even organisms that are better known as nitrogen cyclers, and we couldn't readily explain the methane emissions by something as simple as, for example, how much sulfate is available or how many methanogens are there," said Tringe.

Another concept in ecology is that restoring habitats to their native state can boost carbon storage, improve water quality, and increase wildlife populations. In recent decades, wetlands have been increasingly recognized as critical ecosystems for these environmental services, leading to widespread efforts to restore ecosystems by removing barriers, pollution, and non-native organisms.

Modeling work by co-author Dennis D. Baldocchi, Executive Associate Dean and professor of Biometeorology at UC Berkeley, suggests that although the restored wetland is adding greenhouse gas to the atmosphere currently, the ecosystem will stabilize and begin to serve as a net carbon sink within 100 to 150 years. This may not be the timeline that stakeholders were hoping for when they restored the area with the goal of carbon sequestration.

"We want to know if these systems will act as long-term carbon sinks," said Baldocchi. "And these microbiological investigations can help refine our models and predictions."

Tringe noted that other labs have observed increased methane production from wetland soils with increased salinity. Scientists from Duke University took soil core samples from a coastal freshwater wetland and exposed them to artificial seawater, and artificial seawater lacking sulfate. In both cases, methane production went up. Tringe's lab recently collaborated with Marcelo Ardón of North Carolina State University to analyze the microbial communities in those soils.

"There was this expectation that sulfate would be the most important thing. And in those studies, not only did salt water stimulate methane production, which again is kind of counter to the dogma that sulfate is important, it happened whether you had sulfate there or not; in fact the sulfate didn't have a big effect on the methane emissions," said Tringe. "So I think these experimental manipulations are reconfirming the story that there's more nuanced effects of seawater intrusion than just a sulfate addition, and also more nuanced factors behind ecosystem restoration."

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Beaver activity in the Arctic increases emission of methane greenhouse gas

The climate-driven advance of beavers into the Arctic tundra is causing the release of more methane -- a greenhouse gas -- into the atmosphere.

Beavers, as everyone knows, like to make dams. Those dams cause flooding, which inundates vegetation and turns Arctic streams and creeks into a series of ponds. Those beaver ponds and surrounding inundated vegetation can be devoid of oxygen and rich with organic sediment, which releases methane as the material decays.

Methane is also released when organics-rich permafrost thaws as the result of heat carried by the spreading water.

A study linking Arctic beavers to an increase in the release of methane was published in July in Environmental Research Letters.

The lead author is Jason Clark, a former postdoctoral fellow at the University of Alaska Fairbanks Geophysical Institute. Research Professor Ken Tape, also of the Geophysical Institute, was Clark's adviser and is a co-author. Other co-authors include Benjamin Jones, a research assistant professor at the UAF Institute of Northern Engineering; and researchers from the National Park Service and NASA's Jet Propulsion Laboratory.

Tape has done extensive research about the northward migration of beavers and their resultant impact on the Arctic environment.

"What we found is that there are lots of methane hotspots right next to ponds and they start to diminish as you go away from the pond," he said.

The new study is the first to link large numbers of new beaver ponds to methane emissions at the landscape scale. It suggests that beaver engineering in the Arctic will at least initially increase methane release.

"We say 'initially' because that's the data we have," Tape said. "What the longer-term implications are, we don't know."

As a greenhouse gas, methane is 25 times more potent than carbon dioxide at trapping heat in Earth's atmosphere.

It accounts for about 20 percent of global greenhouse gas emissions, according to the U.S. Environmental Protection Agency. The agency says human activities have more than doubled atmospheric methane concentrations in the past two centuries.

The new research focused on 166 square miles of the lower Noatak River basin in Northwest Alaska. Data was obtained by airborne hyperspectral imaging through NASA's Arctic-Boreal Vulnerability Experiment program. That program and the National Science Foundation funded the research.

Hyperspectral cameras image an area in hundreds of wavelengths across the electromagnetic spectrum, including many not visible to the human eye. That differs from other cameras, which typically only image in the primary colors of red, green and blue.

The researchers compared the location of methane hot spots to the locations of 118 beaver ponds and to a number of nearby unaffected stream reaches and lakes. They analyzed the area up to approximately 200 feet from the perimeter of each water body and found a "significantly greater" number of methane hot spots around beaver ponds.

"We have these datasets that largely overlap, in space and mostly in time," Tape said. "It's kind of a simple design relying on a new tool."

Read more at Science Daily

Shrinking Arctic glaciers are unearthing a new source of methane

As the Arctic warms, shrinking glaciers are exposing bubbling groundwater springs which could provide an underestimated source of the potent greenhouse gas methane, finds new research published today in Nature Geoscience.

The study, led by researchers from the University of Cambridge and the University Centre in Svalbard, Norway, identified large stocks of methane gas leaking from groundwater springs unveiled by melting glaciers.

The research suggests that these methane emissions will likely increase as Arctic glaciers retreat and more springs are exposed. This, and other methane emissions from melting ice and frozen ground in the Arctic, could exacerbate global warming.

"These springs are a considerable, and potentially growing, source of methane emissions -- one that has been missing from our estimations of the global methane budget until now," said Gabrielle Kleber, lead author of the research who is from Cambridge's Department of Earth Sciences.

Scientists are concerned that additional methane emissions released by the Arctic thaw could ramp-up human-induced global warming. The springs the researchers studied hadn't previously been recognized as a potential source of methane emissions.

Kleber spent nearly three years monitoring the water chemistry of more than a hundred springs across Svalbard, where air temperatures are rising two times faster than the average for the Arctic. She likens Svalbard to the canary in the coal mine of global warming, "Since it is warming faster than the rest of the Arctic, we can get a preview of the potential methane release that could happen at a larger scale across this region."

Professor Andrew Hodson, study co-author from the University Centre in Svalbard said, "Living in Svalbard exposes you to the front-line of Arctic climate change. I can't think of anything more stark than the sight of methane outgassing in the immediate forefield of a retreating glacier."

Previously, research has centred on methane release from thawing permafrost (frozen ground). "While the focus is often on permafrost, this new finding tells us that there are other pathways for methane emissions which could be even more significant in the global methane budget," said study co-author Professor Alexandra Turchyn, also from Cambridge's Department of Earth Sciences.

Hodson added, "Until this work was conducted, we didn't understand the source and pathways of this gas because we were reading about studies from completely different parts of the Arctic where glaciers are absent."

The methane-delivering springs they identified are fed by a plumbing system hidden beneath most glaciers, which taps into large groundwater reserves within the underlying sediments and surrounding bedrock. Once the glaciers melt and retreat, springs appear where this groundwater network punches through to the surface.

The researchers found that methane emissions from glacial groundwater springs across Svalbard could exceed 2,000 tonnes over the course of a year -- which equates to roughly 10% of the methane emissions resulting from Norway's annual oil and gas energy industry.

This source of methane will likely become more significant as more springs are exposed, said Kleber, "If global warming continues unchecked then methane release from glacial groundwater springs will probably become more extensive."

Glacial groundwater springs aren't always easy to recognize, so Kleber trained her eye to pick them out from satellite images. Zooming in on the areas of land exposed by the retreat of 78 glaciers across Svalbard, Kleber looked for tell-tale blue trickles of ice where groundwater had leaked to the surface and frozen. She then travelled to each of these sites by snowmobile to take samples of the groundwater at locations where the ice had blistered due to pressurized water and gas build up.

When Kleber and the team profiled the chemistry of the water feeding these springs, they found that all bar one of the sites studied were highly concentrated with dissolved methane -- meaning that, when the spring water reaches the surface, there is plenty of excess methane that can escape to the atmosphere.

The researchers also identified localized hotspots of methane emissions, which were closely related to the type of rock from which the groundwater emerges. Certain rocks like shale and coal contain natural gases, including methane, produced by the breakdown of organic matter when the rocks formed. This methane can move upwards through fractures in the rock and into the groundwater.

"In Svalbard we are beginning to understand the complex and cascading feedbacks triggered by glacier melt -- it seems likely that there are more outcomes like this which we have yet to uncover," said Kleber.

Read more at Science Daily

Potent greenhouse gas produced by industry could be readily abated with existing technologies

Researchers have found that one method of reducing greenhouse gas emissions is available, affordable, and capable of being implemented right now. Nitrous oxide, a potent greenhouse gas and ozone-depleting substance, could be readily abated with existing technology applied to industrial sources.

"The urgency of climate change requires that all greenhouse gas emissions be abated as quickly as is technologically and economically feasible," said lead author Eric Davidson, a professor with the University of Maryland Center for Environmental Science. "Limiting nitrous oxide in an agricultural context is complicated, but mitigating it in industry is affordable and available right now. Here is a low-hanging fruit that we can pluck quickly."

When greenhouse gases are released into the atmosphere, they trap the heat from the sun, leading to a warming planet. In terms of emissions, nitrous oxide is third among greenhouse gases, topped only by carbon dioxide and methane. Also known as laughing gas, it has a global warming potential nearly 300 times that of carbon dioxide and stays in the atmosphere for more than 100 years. It also destroys the protective ozone layer in the stratosphere, so reducing nitrous oxide emissions provides a double benefit for the environment and humanity.

Nitrous oxide concentration in the atmosphere has increased at an accelerating rate in recent decades, mostly from increasing agricultural emissions, which contribute about two-thirds of the global human-caused nitrous oxide. However, agricultural sources are challenging to reduce. In contrast, for the industry and energy sectors, low-cost technologies already exist to reduce nitrous oxide emissions to nearly zero.

Industrial nitrous oxide emissions from the chemical industry are primarily by-products from the production of adipic acid (used in the production of nylon) and nitric acid (used to make nitrogen fertilizers, adipic acid, and explosives). Emissions also come from fossil fuel combustion used in manufacturing and internal combustion engines used in cars and trucks.

"We know that abatement is feasible and affordable. The European Union's emissions trading system made it financially attractive to companies to remove nitrous oxide emissions in all adipic acid and nitric acid plants," said co-author Wilfried Winiwarter of the International Institute for Applied Systems Analysis. "The German government is also helping to fund abatement of nitrous oxide emissions from nitric acid plants in several low-income and middle-income countries."

The private sector could also play a key role in nitrous oxide emissions reduction, encouraged by trends in consumer preferences for purchasing climate-friendly products. For example, 65% of the nitrous emissions embodied in nylon products globally are used in passenger cars and light vehicles. Automobile manufacturers could require supply chains to source nylon exclusively from plants that deploy efficient nitrous oxide abatement technology.

Read more at Science Daily

Greenhouse gas emissions at 'an all-time high' -- and it is causing an unprecedented rate of global warming, say scientists

Human-caused global warming has continued to increase at an "unprecedented rate" since the last major assessment of the climate system published two years ago, say 50 leading scientists.

One of the researchers said the analysis was a "timely wake-up call" that the pace and scale of climate action has been insufficient, and it comes as climate experts meet in Bonn to prepare the ground for the major COP28 climate conference in the UAE in December, which will include a stocktake of progress towards keeping global warming to 1.5°C by 2050.

Given the speed at which the global climate system is changing, the scientists argue that policymakers, climate negotiators and civil society groups need to have access to up-to-date and robust scientific evidence on which to base decisions.

The authoritative source of scientific information on the state of the climate is the UN's Intergovernmental Panel on Climate Change (IPCC) but the turnaround time for its major assessments is five or ten years, and that creates an "information gap," particularly when climate indicators are changing rapidly.

In an initiative being led by the University of Leeds, the scientists have developed an open data, open science platform -- the Indicators of Global Climate Change and website (https://igcc.earth/). It will update information on key climate indicators every year.

Critical decade for climate change

The Indicators of Global Climate Change Project is being co-ordinated by Professor Piers Forster, Director of the Priestley Centre for Climate Futures at Leeds. He said: "This is the critical decade for climate change.

"Decisions made now will have an impact on how much temperatures will rise and the degree and severity of impacts we will see as a result.

"Long-term warming rates are currently at a long-term high, caused by highest-ever levels of greenhouse gas emissions. But there is evidence that the rate of increase in greenhouse gas emissions has slowed.

"We need to be nimble footed in the face of climate change. We need to change policy and approaches in the light of the latest evidence about the state of the climate system. Time is no longer on our side. Access to up-to-date information is vitally important."

Writing in the journal Earth System Science Data, the scientists have revealed how key indicators have changed since the publication of the IPCC's Sixth Assessment Working Group 1 report in 2021- which produced the key data that fed into the subsequent IPCC Sixth Synthesis Report.

What the updated indicators show

Human-induced warming, largely caused by the burning of fossil fuels, reached an average of 1.14°C for the most recent decade (2013 to 2022) above pre-industrial levels. This is up from 1.07°C between 2010 and 2019.

Human-induced warming is now increasing at a pace of over 0.2°C per decade.

The analysis also found that greenhouse gas emissions were "at an all-time high," with human activity resulting in the equivalent of 54 (+/-5.3) gigatonnes (or billion metric tonnes) of carbon dioxide being released into the atmosphere on average every year over the last decade (2012-2021).

There has been positive move away from burning coal, yet this has come at a short-term cost in that it has added to global warming by reducing particulate pollution in the air, which has a cooling effect.

'Indicators critical to address climate crisis'

Professor Maisa Rojas Corradi, Minister of the Environment in Chile, IPCC author and a scientist involved in this study, said: "An annual update of key indicators of global change is critical in helping the international community and countries to keep the urgency of addressing the climate crisis at the top of the agenda and for evidence-based decision-making.

"In line with the "ratchet-mechanism" of increasing ambition envisioned by the Paris Agreement we need scientific information about emissions, concentration, and temperature as often as possible to keep international climate negotiations up to date and to be able to adjust and if necessary correct national policies.

"In the case of Chile, we have a climate change law that aims at aligning government-wide policies with climate action."

Remaining carbon budget

One of the major findings of the analysis is the rate of decline in what is known as the remaining carbon budget, an estimate of how much carbon that can be released into the atmosphere to give a 50% chance of keeping global temperature rise within 1.5°C.

In 2020, the IPCC calculated the remaining carbon budget was around 500 gigatonnes of carbon dioxide. By the start of 2023, the figure was roughly half that at around 250 gigatonnes of carbon dioxide.

The reduction in the estimated remaining carbon budget is due to a combination of continued emissions since 2020 and updated estimates of human-induced warming.

Professor Forster said: "Even though we are not yet at 1.5°C warming, the carbon budget will likely be exhausted in only a few years as we have a triple whammy of heating from very high CO2 emissions, heating from increases in other GHG emissions and heating from reductions in pollution.

"If we don't want to see the 1.5°C goal disappearing in our rearview mirror, the world must work much harder and urgently at bringing emissions down.

"Our aim is for this project to help the key players urgently make that important work happen with up-to-date and timely data at their fingertips."

Dr Valérie Masson-Delmotte, from the Université Paris Saclay who co-chaired Working Group 1 of the IPCC's Sixth Assessment report and was involved in the climate indicators project, said: "This robust update shows intensifying heating of our climate driven by human activities. It is a timely wake up call for the 2023 global stocktake of the Paris Agreement -- the pace and scale of climate action is not sufficient to limit the escalation of climate-related risks."

As recent IPCC reports have conclusively shown, with every further increment of global warming, the frequency and intensity of climate extremes, including hot extremes, heavy rainfall and agricultural droughts, increases.

The Indicators of Global Climate Change (https://igcc.earth/) will have annually updated information on greenhouse gas emissions, human-induced global warming and the remaining carbon budget.

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Extinct offshore volcano could store gigatons of carbon dioxide

A new study published in Geology concludes that an extinct volcano off the shore of Portugal could store as much as 1.2-8.6 gigatons of carbon dioxide, the equivalent of ~24-125 years of the country's industrial emissions. For context, in 2022 a total of 42.6 megatons (0.0426 gigatons) of carbon dioxide was removed from the atmosphere by international carbon capture and storage efforts, according to the Global CCS Institute. The new study suggests that carbon capture and storage in offshore underwater volcanoes could be a promising new direction for removal and storage of much larger volumes of the greenhouse gas from the atmosphere.

"We know that most countries, including Portugal, are making efforts to decarbonize the economy and our human activities, this is a message that this may be one of the instruments to solve the problem" says Ricardo Pereira, a geologist at the NOVA School of Science and Technology, and co-author of the study.

Storing carbon dioxide in an extinct volcano would rely on a process known as 'in situ mineral carbonation.' In this process, carbon dioxide reacts with elements in certain types of rocks to produce new minerals that safely and permanently store the carbon dioxide. Elements like calcium, magnesium, and iron combine with carbon dioxide to form the minerals calcite, dolomite, and magnesite, respectively. Rocks that contain large amounts of calcium, iron, and magnesium are ideal candidates for this process -- such as the volcanic basalts that make up most of the sea floor. Knowing this, the researchers targeted an offshore volcano for a few reasons -- the structure of the volcano could provide an ideal architecture for carbon injection and storage, the rocks are the right type for the reactions involved, and the location Is not too close to large populations, but also not too far.

Most carbon capture projects have relied on injection of carbon dioxide into porous sedimentary basins that are sealed to prevent migration of the gas out of reservoirs. In these cases, the carbon will eventually start to form minerals, but only over longer periods of time -- decades to centuries. In 2016, researchers published findings that 95% of carbon dioxide injected into underground basalts in Iceland had mineralized within just two years. The much shorter mineralization time makes the process safer and more effective -- once carbon is stored in minerals, issues like potential leaks are no longer a concern.

Davide Gamboa, a geologist at the University of Aveiro and co-author of the study, explains, "What makes mineral carbonation really interesting is the time. The faster it gets into a mineral, the safer it becomes, and once it's a mineral, it is permanent."

The researchers studied the storage potential at the ancient Fontanelas volcano, which is partially buried ~100 kilometers offshore from Lisbon, with a peak ~1500 meters below sea-level.

To estimate the potential volume of carbon dioxide that could be stored at this site, the authors used 2D and 3D seismic studies of the undersea volcano that had been produced during offshore oil exploration, as well as data from samples that had been dredged from the area in 2008. The dredged samples contained naturally formed carbonate minerals, indicating that the chemical reactions required to store carbon were already happening, and that intentional efforts to mineralize carbon in these rocks should be successful. The samples also had up to 40% pore space -- meaning there are spaces within the rocks where carbon dioxide could be injected and mineralized. The researchers also indicate that low-permeability layers imaged around the flanks of the volcano could help with containing the carbon dioxide before it is mineralized.

Read more at Science Daily

Greenhouse gas release from permafrost is influenced by mineral binding processes

About a quarter of the organic carbon contained in ice-rich Arctic permafrost is more difficult for microorganisms to utilize. The reason for this is a strong binding of the organic material originating from dead plant remains to mineral soil particles. That is the result of a study conducted by a research group led by Professor Dr Janet Rethemeyer and Dr Jannik Martens at the University of Cologne's Institute of Geology and Mineralogy. Accurate predictions of the release of greenhouse gases from permafrost deposits are therefore more complex than previously assumed.

The results of the joint project, which was funded by the German Federal Ministry of Education and Research (BMBF), are published in the article 'Stabilization of mineral-associated organic carbon in Pleistocene permafrost' in the journal Nature Communications.

The Arctic is warming dramatically fast compared to other parts of the world. Much of it is covered by permafrost and contains large amounts of carbon, almost twice as much as the atmosphere. This carbon comes from plants that have grown over thousands of years, decomposed in the soil and then become 'frozen'. Due to strongly rising temperatures in the Arctic, this gigantic freezer is thawing fast. The old carbon stored in it can now be degraded by microorganisms, releasing carbon dioxide and methane into the atmosphere. These greenhouse gases accelerate global warming. The warmer it gets, the more greenhouse gases are in turn released from the permafrost, causing temperatures to rise further and frozen soils and sediments to thaw even faster. "There is a feedback of carbon in permafrost with climate, the strength of which depends largely on those factors that influence microbial degradation," said Janet Rethemeyer.

In the joint research project, scientists from the Institute of Zoology at the University of Cologne, the University of Tübingen, the Technical University of Munich and the Alfred-Wegener-Institute in Potsdam studied long permafrost cores from the Siberian Arctic. The cores come from very ice-rich, fine-grained sediments -- similar to loess in our latitudes -- that were deposited in large areas of Siberia and Alaska during the last ice age. The cores, up to 12 metres long, comprise sediments deposited over a period of up to 55,000 years.

The analyses of the permafrost cores show that a significant part (25-35 %) of the carbon is associated with the mineral particles and thus more difficult to access for microorganisms. "Predictions of interactions between thawing permafrost and climate are very complicated because the microbial degradability of the organic material in the sediments has varied greatly over the last 55,000 years. This is due to the different climatic conditions during this long period of deposition," Janet Rethemeyer explained. Warmer and wetter conditions resulted in poorer binding of carbon to the mineral particles, while a colder and drier climate led to stronger binding, primarily to iron oxides. Stronger binding to iron oxides means that the decomposition rates of old plant material are lower, as Professor Dr. Michael Bonkowski from the Institute of Zoology, Department of Terrestrial Ecology at the University of Cologne has shown in laboratory experiments.

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Colorful films could help buildings, cars keep their cool

The cold blast of an air conditioner can be a welcome relief as temperatures soar, but "A/C" units require large amounts of energy and can leak potent greenhouse gases. Today, scientists report an eco-friendly alternative -- a plant-based film that gets cooler when exposed to sunlight and comes in a variety of textures and bright, iridescent colors. The material could someday keep buildings, cars and other structures cool without requiring external power.

The researchers will present their results at the spring meeting of the American Chemical Society (ACS).

"To make materials that remain cooler than the air around them during the day, you need something that reflects a lot of solar light and doesn't absorb it, which would transform energy from the light into heat," says Silvia Vignolini, Ph.D., the project's principal investigator. "There are only a few materials that have this property, and adding color pigments would typically undo their cooling effects," Vignolini adds.

Passive daytime radiative cooling (PDRC) is the ability of a surface to emit its own heat into space without it being absorbed by the air or atmosphere. The result is a surface that, without using any electrical power, can become several degrees colder than the air around it. When used on buildings or other structures, materials that promote this effect can help limit the use of air conditioning and other power-intensive cooling methods.

Some paints and films currently in development can achieve PDRC, but most of them are white or have a mirrored finish, says Qingchen Shen, Ph.D., who is presenting the work at the meeting. Both Vignolini and Shen are at Cambridge University (U.K.). But a building owner who wanted to use a blue-colored PDRC paint would be out of luck -- colored pigments, by definition, absorb specific wavelengths of sunlight and only reflect the colors we see, causing undesirable warming effects in the process.

But there's a way to achieve color without the use of pigments. Soap bubbles, for example, show a prism of different colors on their surfaces. These colors result from the way light interacts with differing thicknesses of the bubble's film, a phenomenon called structural color. Part of Vignolini's research focuses on identifying the causes behind different types of structural colors in nature. In one case, her group found that cellulose nanocrystals (CNCs), which are derived from the cellulose found in plants, could be made into iridescent, colorful films without any added pigment.

As it turns out, cellulose is also one of the few naturally occurring materials that can promote PDRC. Vignolini learned this after hearing a talk from the first researchers to have created a cooling film material. "I thought wow, this is really amazing, and I never really thought cellulose could do this."

In recent work, Shen and Vignolini layered colorful CNC materials with a white-colored material made from ethyl cellulose, producing a colorful bi-layered PDRC film. They made films with vibrant blue, green and red colors that, when placed under sunlight, were an average of nearly 40 F cooler than the surrounding air. A square meter of the film generated over 120 Watts of cooling power, rivaling many types of residential air conditioners. The most challenging aspect of this research, Shen says, was finding a way to make the two layers stick together -- on their own, the CNC films were brittle, and the ethyl cellulose layer had to be plasma-treated to get good adhesion. The result, however, was films that were robust and could be prepared several meters at a time in a standard manufacturing line.

Since creating these first films, the researchers have been improving their aesthetic appearance. Using a method modified from approaches previously explored by the group, they're making cellulose-based cooling films that are glittery and colorful. They've also adjusted the ethyl cellulose film to have different textures, like the differences between types of wood finishes used in architecture and interior design, says Shen. These changes would give people more options when incorporating PDRC effects in their homes, businesses, cars and other structures.

The researchers now plan to find ways they can make their films even more functional. According to Shen, CNC materials can be used as sensors to detect environmental pollutants or weather changes, which could be useful if combined with the cooling power of their CNC-ethyl cellulose films. For example, a cobalt-colored PDRC on a building façade in a car-dense, urban area could someday keep the building cool and incorporate detectors that would alert officials to higher levels of smog-causing molecules in the air.

Read more at Science Daily

How to pull carbon dioxide out of seawater

As carbon dioxide continues to build up in the Earth's atmosphere, research teams around the world have spent years seeking ways to remove the gas efficiently from the air. Meanwhile, the world's number one "sink" for carbon dioxide from the atmosphere is the ocean, which soaks up some 30 to 40 percent of all of the gas produced by human activities.

Recently, the possibility of removing carbon dioxide directly from ocean water has emerged as another promising possibility for mitigating CO2 emissions, one that could potentially someday even lead to overall net negative emissions. But, like air capture systems, the idea has not yet led to any widespread use, though there are a few companies attempting to enter this area.

Now, a team of researchers at MIT says they may have found the key to a truly efficient and inexpensive removal mechanism. The findings were reported this week in the journal Energy and Environmental Science, in a paper by MIT professors T. Alan Hatton and Kripa Varanasi, postdoc Seoni Kim, and graduate students Michael Nitzsche, Simon Rufer, and Jack Lake.

The existing methods for removing carbon dioxide from seawater apply a voltage across a stack of membranes to acidify a feed stream by water splitting. This converts bicarbonates in the water to molecules of CO2, which can then be removed under vacuum. Hatton, who is the Ralph Landau Professor of Chemical Engineering, notes that the membranes are expensive, and chemicals are required to drive the overall electrode reactions at either end of the stack, adding further to the expense and complexity of the processes. "We wanted to avoid the need for introducing chemicals to the anode and cathode half cells and to avoid the use of membranes if at all possible" he says.

The team came up with a reversible process consisting of membrane-free electrochemical cells. Reactive electrodes are used to release protons to the seawater fed to the cells, driving the release of the dissolved carbon dioxide from the water. The process is cyclic: It first acidifies the water to convert dissolved inorganic bicarbonates to molecular carbon dioxide, which is collected as a gas under vacuum. Then, the water is fed to a second set of cells with a reversed voltage, to recover the protons and turn the acidic water back to alkaline before releasing it back to the sea. Periodically, the roles of the two cells are reversed once one set of electrodes is depleted of protons (during acidification) and the other has been regenerated during alkalization.

This removal of carbon dioxide and reinjection of alkaline water could slowly start to reverse, at least locally, the acidification of the oceans that has been caused by carbon dioxide buildup, which in turn has threatened coral reefs and shellfish, says Varanasi, a professor of mechanical engineering. The reinjection of alkaline water could be done through dispersed outlets or far offshore to avoid a local spike of alkalinity that could disrupt ecosystems, they say.

"We're not going to be able to treat the entire planet's emissions," Varanasi says. But the reinjection might be done in some cases in places such as fish farms, which tend to acidify the water, so this could be a way of helping to counter that effect.

Once the carbon dioxide is removed from the water, it still needs to be disposed of, as with other carbon removal processes. For example, it can be buried in deep geologic formations under the sea floor, or it can be chemically converted into a compound like ethanol, which can be used as a transportation fuel, or into other specialty chemicals. "You can certainly consider using the captured CO2 as a feedstock for chemicals or materials production, but you're not going to be able to use all of it as a feedstock," says Hatton. "You'll run out of markets for all the products you produce, so not matter what, a significant amount of the captured CO2 will need to be buried underground."

Initially at least, the idea would be to couple such systems with existing or planned infrastructure that already processes seawater, such as desalination plants. "This system is scalable so that we could integrate it potentially into existing processes that are already processing ocean water or in contact with ocean water," Varanasi says. There, the carbon dioxide removal could be a simple add-on to existing processes, which already return vast amounts of water to the sea, and it would not require consumables like chemical additives or membranes.

"With desalination plants, you're already pumping all the water, so why not co-locate there?" Varanasi says. "A bunch of capital costs associated with the way you move the water, and the permitting, all that could already be taken care of."

The system could also be implemented by ships that would process water as they travel, in order to help mitigate the significant contribution of ship traffic to overall emissions. There are already international mandates to lower shipping's emissions, and "this could help shipping companies offset some of their emissions, and turn ships into ocean scrubbers," Varanasi says.

The system could also be implemented at locations such as offshore drilling platforms, or at aquaculture farms. Eventually, it could lead to a deployment of free-standing carbon removal plants distributed globally.

The process could be more efficient than air-capture systems, Hatton says, because the concentration of carbon dioxide in seawater is more than 100 times greater than it is in air. In direct air-capture systems it is first necessary to capture and concentrate the gas before recovering it. "The oceans are large carbon sinks, however, so the capture step has already kind of been done for you," he says. "There's no capture step, only release." That means the volumes of material that need to be handled are much smaller, potentially simplifying the whole process and reducing the footprint requirements.

The research is continuing, with one goal being to find an alternative to the present step that requires a vacuum to remove the separated carbon dioxide from the water. Another need is to identify operating strategies to prevent precipitation of minerals that can foul the electrodes in the alkalinization cell, an inherent issue that reduces the overall efficiency in all reported approaches. Hatton notes that significant progress has been made on these issues, but that it is still too early to report on them. The team expects that the system could be ready for a practical demonstration project within about two years.

Read more at Science Daily

Monitoring an 'anti-greenhouse' gas: Dimethyl sulfide in Arctic air

Data stored in ice cores dating back 55 years bring new insight into atmospheric levels of a molecule that can significantly affect weather and climate.

Dimethyl sulfide (C2H6S) is a small molecule released by phytoplankton in the ocean, which can play a big role in regulating the Earth's climate. It encourages cloud formation above the sea, and is often called an 'anti-greenhouse gas', since clouds block radiation from the sun and lower sea surface temperatures. At least some blocked heat will be retained in the atmosphere, however, so the effects can be complex. Researchers at Hokkaido University have charted evidence for increasing dimethyl sulfide emissions linked to the retreat of sea ice from Greenland as the planet warms. They report their findings in the journal Communications Earth & Environment.

Modelling studies have long suggested that the decline in Arctic sea ice could lead to increased dimethyl sulfide emission, but direct evidence for this has been lacking. Assistant Professor Sumito Matoba and colleagues have inferred dimethyl sulfide levels over 55 years by quantifying the related compound, methane sulfonic acid (MSA), in ice core samples from the south-east Greenland ice sheet. MSA is directly produced from dimethyl sulfide, serving as a stable record of dimethyl sulfide levels. This process is part of a variety of chemical interactions among aerosols in the atmosphere.

The team, including researchers from Nagoya University and Japan's Aerospace Exploration Agency, reconstructed the annual and seasonal MSA flux from 1960 to 2014, at a monthly resolution. The annual MSA levels decreased from 1960 to 2001, but then markedly increased after 2002.

"We found that July to September MSA fluxes were three to six times higher between 2002 and 2014 than between 1972 and 2001," says Matoba. "We attribute this to the earlier retreat of sea ice in recent years."

Supporting evidence comes from satellite data that has monitored the levels of the crucial sunlight-absorbing green pigment chlorophyll-a in the surrounding seas. The chlorophyll-a serves as an indicator of phytoplankton abundance, which in turn should correlate well with the amount of dimethyl sulfide released by the phytoplankton.

Arctic temperatures are rising twice as fast as the global average, and the summer seasonal sea ice extent has declined sharply in recent decades. This increases the amount of light striking the ocean and promotes the growth of phytoplankton.

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Solar-powered system converts plastic and greenhouse gases into sustainable fuels

Researchers have developed a system that can transform plastic waste and greenhouse gases into sustainable fuels and other valuable products -- using just the energy from the Sun.

The researchers, from the University of Cambridge, developed the system, which can convert two waste streams into two chemical products at the same time -- the first time this has been achieved in a solar-powered reactor.

The reactor converts the carbon dioxide (CO2) and plastics into different products that are useful in a range of industries. In tests, CO2 was converted into syngas, a key building block for sustainable liquid fuels, and plastic bottles were converted into glycolic acid, which is widely used in the cosmetics industry. The system can easily be tuned to produce different products by changing the type of catalyst used in the reactor.

Converting plastics and greenhouse gases -- two of the biggest threats facing the natural world -- into useful and valuable products using solar energy is an important step in the transition to a more sustainable, circular economy. The results are reported in the journal Nature Synthesis.

"Converting waste into something useful using solar energy is a major goal of our research," said Professor Erwin Reisner from the Yusuf Hamied Department of Chemistry, the paper's senior author. "Plastic pollution is a huge problem worldwide, and often, many of the plastics we throw into recycling bins are incinerated or end up in landfill."

Reisner also leads the Cambridge Circular Plastics Centre (CirPlas), which aims to eliminate plastic waste by combining blue-sky thinking with practical measures.

Other solar-powered 'recycling' technologies hold promise for addressing plastic pollution and for reducing the amount of greenhouse gases in the atmosphere, but to date, they have not been combined in a single process.

"A solar-driven technology that could help to address plastic pollution and greenhouse gases at the same time could be a game-changer in the development of a circular economy," said Subhajit Bhattacharjee, the paper's co-first author.

"We also need something that's tuneable, so that you can easily make changes depending on the final product you want," said co-first author Dr Motiar Rahaman.

The researchers developed an integrated reactor with two separate compartments: one for plastic, and one for greenhouse gases. The reactor uses a light absorber based on perovskite -- a promising alternative to silicon for next-generation solar cells.

The team designed different catalysts, which were integrated into the light absorber. By changing the catalyst, the researchers could then change the end product. Tests of the reactor under normal temperature and pressure conditions showed that the reactor could efficiently convert PET plastic bottles and CO2 into different carbon-based fuels such as CO, syngas or formate, in addition to glycolic acid. The Cambridge-developed reactor produced these products at a rate that is also much higher than conventional photocatalytic CO2 reduction processes.

"Generally, CO2 conversion requires a lot of energy, but with our system, basically you just shine a light at it, and it starts converting harmful products into something useful and sustainable," said Rahaman. "Prior to this system, we didn't have anything that could make high-value products selectively and efficiently."

"What's so special about this system is the versatility and tuneability -- we're making fairly simple carbon-based molecules right now, but in future, we could be able to tune the system to make far more complex products, just by changing the catalyst," said Bhattacharjee.

Reisner recently received new funding from the European Research Council to help the development of their solar-powered reactor. Over the next five years, they hope to further develop the reactor to produce more complex molecules. The researchers say that similar techniques could someday be used to develop an entirely solar-powered recycling plant.

"Developing a circular economy, where we make useful things from waste instead of throwing it into landfill, is vital if we're going to meaningfully address the climate crisis and protect the natural world," said Reisner. "And powering these solutions using the Sun means that we're doing it cleanly and sustainably."

Read more at Science Daily

Earth's many new lakes

The number of lakes on our planet has increased substantially in recent decades, according to a unique global survey of 3.4 million lakes that the University of Copenhagen has taken part in. There has been a particular increase in the number of small lakes, which unfortunately, emit large amounts of greenhouse gas. The development is of great importance for Earth's carbon account, global ecosystems, and human access to water resources.

Bacteria and fungi feeding on dead plants and animals at the bottom of a lake emit vast amounts of CO2, methane, nitrous oxide, and other gases. Some of these gases end up in the atmosphere. This mechanism causes lakes to act like greenhouse gas factories. In fact, freshwater lakes probably account for 20% of all global CO2 fossil fuel emissions into Earth's atmosphere. Forecasts suggest that climate change will cause lakes to emit an ever-greater share of greenhouse gases in the future.

This is just one of the reasons why it is important to know how many and how big these lakes are, as well as how they develop. Until now, this information was unknown. Scientific researchers from the University of Copenhagen and other universities have now prepared a more accurate and detailed map of the world's lakes than has ever existed. The researchers mapped 3.4 million lakes and their evolution over the past four decades using high-resolution satellite imagery combined with artificial intelligence.

The survey shows that between 1984 and 2019, the area of global lake surfaces grew by over 46,000 km2 -- slightly more than the surface area of Denmark.

"There have been major and rapid changes with lakes in recent decades that affect greenhouse gas accounts, as well as ecosystems and access to water resources. Among other things, our newfound knowledge of the extent and dynamics of lakes allows us to better calculate their potential carbon emissions," explains Jing Tang, an Assistant Professor at the Department of Biology and co-author of the study, which is now published in Nature Communications.

According to the study's calculations, the annual increase of CO2 emissions from lakes during the period is 4.8 teragrams (10^12, trillion) of carbon -- which equals to the CO2 emission increase of the United Kingdom in 2012.

Small lakes, large CO2 emissions

More and more small lakes (<1 km2) have appeared since 1984. The number of these small lakes is especially important according to the researchers, because they emit the most greenhouse gas in relation to their size. While small lakes account for just 15% of total lake area, they account for 25% of CO2 and 37% of methane emissions. Furthermore, they also contribute to 45% and 59% of the net increases of the lake CO2 and CH4 emissionsover the period 1984-2019.

"Small lakes emit a disproportionate amount of greenhouse gases because they typically accumulate more organic matter, which is converted into gases. And also, because they are often shallow. This makes it easier for gases to reach the surface and up into the atmosphere," explains Jing Tang, who continues:

"At the same time, small lakes are much more sensitive to changes in climate and weather, as well as to human disturbances. As a result, their sizes and water chemistry fluctuate greatly. Thus, while it is important to identify and map them, it is also more demanding. Fortunately, we've been able to do justify that."

The mapping also reveals that there are two main reasons for Earth's many new lakes: climate change and human activities. Reservoirs account for more than half of increased lake area -- i.e., artificial lakes. The other half are primarily created by melting glaciers or thawing permafrost.

New figures sent to the UN

According to the researchers, the new dataset offers a range of regional and global applications.

"I have sent our new greenhouse gas emission estimates to the people responsible for calculating the global carbon budget, those who are behind the UN's IPCC climate reports. I hope they include them in updating the global emission numbers," says Jing Tang.

She adds:

"Furthermore, the dataset can be used to make better estimates of water resources in freshwater lakes and to better assess the risk of flooding, as well as for better lake management -- because lake area impacts biodiversity too."

Read more at Science Daily

Scientists crack upcycling plastics to reduce greenhouse gas emissions

Scientists from the University of Illinois Urbana-Champaign, University of California, Santa Barbara, and Dow have developed a breakthrough process to transform the most widely produced plastic -- polyethylene (PE) -- into the second-most widely produced plastic, polypropylene (PP), which could reduce greenhouse gas emissions (GHG).

"The world needs more and better options for extracting the energy and molecular value from its waste plastics," said co-lead author Susannah Scott, Distinguished Professor and Mellichamp Chair of Sustainable Catalytic Processing at UC Santa Barbara. Conventional plastic recycling methods result in low-value plastic molecules and, thus, offer little incentive to recycle the mountains of plastic waste that have accumulated over the past several decades. But, Scott added, "turning polyethylene into propylene, which can then be used to make a new polymer, is how we start to build a circular economy for plastics."

"We started by conceptualizing this approach and demonstrated its promise first through theoretical modeling -- now we have proved that it can be done experimentally in a way that is scalable and potentially applicable to current industry demands," said co-lead author Damien Guironnet, a professor of chemical and biomolecular engineering at Illinois, who published the first study outlining the necessary catalytic reactions in 2020.

The new study published in the Journal of the American Chemical Society announces a series of coupled catalytic reactions that transform PE, which is #2 and #4 plastic that make up 29% of the world's plastic consumption, into the building block propylene that is the key ingredient to produce PP, also known as #5 plastic that accounts for close to 25% of the world's plastic consumption.

This study establishes a proof-of-concept for upcycling PE plastic with more than 95% selectivity into propylene. The researchers have built a reactor that creates a continuous flow of propylene that can be converted into PP easily using current technology -- making this discovery scalable and rapidly implementable.

"Our preliminary analysis suggests that if just 20% of the world's PE could be recovered and converted via this route, it could represent a potential savings of GHG emissions comparable to taking 3 million cars off the road," said Garrett Strong, a graduate student associated with the project.

The goal is to cut each very long PE molecule many times to obtain many small pieces, which are the propylene molecules. First, a catalyst removes hydrogen from the PE, creating a reactive location on the chain. Next, the chain is split in two at this location using a second catalyst, which caps the ends using ethylene. Finally, a third catalyst moves the reactive site along the PE chain so the process can be repeated. Eventually, all that is left are a large number of propylene molecules.

"Think of cutting a baguette in half, and then cutting precisely-sized pieces off the end of each half -- where the speed at which you cut controls the size of each slice," Guironnet said.

"Now that we have established the proof of concept, we can start to improve the efficiency of the process by designing catalysts that are faster and more productive, making it possible to scale up," Scott said. "Since our end-product is already compatible with current industry separation processes, better catalysts will make it possible to implement this breakthrough rapidly."

The work presented in this publication is highly complementary to a paper published in Science last week. Both groups used virgin plastics and similar chemistries. However, the Science team used a different process in an enclosed batch reactor, requiring much higher pressure -- which is energy intensive -- and the need to recycle more ethylene.

"If we are to upcycle a significant fraction of the over 100 million tons of plastic waste we generate each year, we need solutions that are highly scalable," Guironnet said. "Our team demonstrated the chemistry in a flow reactor we developed to produce propylene highly selectively and continuously. This is a key advance to address the immense volume of the problem that we are facing."

Read more at Science Daily

System to create bioplastics

A team of Texas A&M AgriLife Research scientists has developed a system that uses carbon dioxide, CO2, to produce biodegradable plastics, or bioplastics, that could replace the nondegradable plastics used today. The research addresses two challenges: the accumulation of nondegradable plastics and the remediation of greenhouse gas emissions.

Published Sept. 28 in Chem, the research was a collaboration of Susie Dai, Ph.D., associate professor in the Texas A&M Department of Plant Pathology and Microbiology, and Joshua Yuan, Ph.D., formerly with the Texas A&M Department of Plant Pathology and Microbiology as chair for synthetic biology and renewable products and now Lopata professor and chair in the Washington University in St. Louis Department of Energy, Environmental and Chemical Engineering.

The research was made possible by the John '90 and Sally '92 Hood Fund for Sustainability and Renewable Products, Texas A&M AgriLife and Texas A&M University.

Creating bioplastics

Dai said today's petroleum-based plastics do not degrade easily and create a massive issue in the ecosystems and, ultimately, oceans.

To address these issues, the Texas A&M College of Agriculture and Life Sciences researchers and their teams worked for almost two years to develop an integrated system that uses CO2 as a feedstock for bacteria to grow in a nutrient solution and produce bioplastics. Peng Zhang, Ph.D., postdoctoral research associate, and Kainan Chen, doctoral student, both in the Texas A&M Department of Plant Pathology and Microbiology, contributed to the work. The Texas A&M University System has filed a patent application for the integrated system.

"Carbon dioxide has been used in concert with bacteria to produce many chemicals, including bioplastics, but this design produces a highly efficient, smooth flow through our carbon dioxide-to-bioplastics pipeline," Dai said.

"In theory, it is kind of like a train with units connected to each other," Dai said. "The first unit uses electricity to convert the carbon dioxide to ethanol and other two-carbon molecules -- a process called electrocatalysis. In the second unit, the bacteria consume the ethanol and carbon molecules to become a machine to produce bioplastics, which are different from petroleum-based plastic polymers that are harder to degrade."

Capturing and re-using CO2 waste

Using CO2 in the process could also help reduce greenhouse gas emissions. Many manufacturing processes emit CO2 as a waste product.

"If we can capture the waste carbon dioxide, we reduce greenhouse gas emission and can use it as a feedstock to produce something," Dai said. "This new platform has great potential to address sustainability challenges and transform the future design of carbon dioxide reduction."

The major strength of the new platform is a much faster reaction rate than photosynthesis and higher energy efficiency.

"We are expanding the capacity of this platform to broad product areas such as fuels, commodity chemicals and diverse materials," Dai said. "The study demonstrated the blueprint for 'decarbonized biomanufacturing' that could transform our manufacturing sector."

Expanding future impacts

Dai said currently, bioplastics are more expensive than petroleum-based plastics. But if the technology is successful enough to produce bioplastics at an economic scale, industries could replace traditional plastic products with ones that have fewer negative environmental impacts. In addition, mitigating CO2 emissions from energy sectors such as gas and electric facilities would also be a benefit.

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A 50% reduction in emissions by 2030 can be achieved. Here's how

The United States has set an ambitious goal to reduce greenhouse gas (GHG) emissions by at least 50% by 2030. Are we on track to succeed?

A new study by a team of scientists and policy analysts from across the nation suggests that there are multiple pathways to achieve this goal -- but big commitments will need to be made, immediately.

"This study should give policy makers and other energy stakeholders some level of comfort, by showing that everybody in the field is pointing in the same direction. The case for clean energy is stronger than ever before and our study shows that the 2030 emission target can be achieved," said Nikit Abhyankar, one of the study's authors and a scientist in the Electricity Markets & Policy Department at Lawrence Berkeley National Laboratory (Berkeley Lab). He notes that the most urgent actions will be to double the amount of renewable capacity built each year and transition predominately to electric vehicles within the next decade or so.

"With the right policies and infrastructure, we can reduce our emissions, while saving American consumers billions of dollars and generating new employment," he said.

Reducing GHG emissions by 50% by 2030 would put the United States on a path to limit global warming to 1.5 degrees Celsius, the target scientists say is required to avoid the worst consequences of the climate crisis.

The study, published in Science, consolidates findings from six recently published techno-economic models that simulate the U.S. energy system operations in comprehensive detail. According to the authors, the separate models all agree on four major points:
 

• The majority of the country's greenhouse gas emissions come from power generation and transportation, so to reduce overall emissions by 50%, the electricity grid needs to run on 80% clean energy (up from today's 40%), and the majority of vehicles sold by 2030 need to be electric. Other important sources of GHG emissions reduction include electrification of buildings and industries.
• The primary barrier to increased alternative energy use will not be cost, it will be enacting new policies. A coordinated policy response between states and the federal government will be necessary to succeed.
• Thanks to advances in wind, solar, and energy storage technologies, powering the electric grid with renewables will not be more expensive; and electric vehicles could save every household up to $1,000 per year in net benefits.
• A clean-energy transition would reduce air pollution, prevent up to 200,000 premature deaths, and avoid up to $800 billion in environmental and health costs through 2050. Many of the health benefits will occur in communities of color and frontline communities that are disproportionately exposed to vehicle, power plant, and industrial pollution.

"Our study provides the first detailed roadmap for how the United States can reach its 50% greenhouse gas emissions-reduction target by 2030," said lead author John Bistline, program manager in the Energy Systems and Climate Analysis Group at the Electric Power Research Institute. "This will require tripling the pace of historic carbon reductions, an ambitious but achievable target if stakeholders collaborate across all sectors. By comparing results across six independent models, we provide greater confidence about the policies and technology deployment needed to achieve near-term climate goals, laying the groundwork for an affordable, reliable, and equitable net-zero future."

According to Abhyankar, who led the development of one of the six models, "By 2030, wind, solar, coupled with energy storage can provide the bulk of the 80% clean electricity. The findings also show that generating the remaining 20% of grid power won't require the creation of new fossil fuel generators." He noted that existing gas plants, used infrequently and combined with energy storage, hydropower, and nuclear power are sufficient to meet demand during periods of extraordinarily low renewable energy generation or exceptionally high electricity demand. "And if the right policies are in place, the coal and gas power plants in the country that currently provide the majority of the nation's electricity would recover their initial investment, thereby avoiding risk of cost under-recovery for investors."

"Since announcing the nation's emissions reduction pledge at the 2021 United Nations climate conference, the United States has taken steps in the right direction," said Abhyankar. "But a lot still needs to happen. What we are hoping is that this study will give some level of a blueprint of how it could be done."

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No glacial fertilization effect in the Antarctic Ocean

Changes in the concentration of atmospheric carbon dioxide (CO2) are considered to be the main cause of past and future climate change. A long-standing debate centers on whether the roughly 30 percent lower CO2 content of the ice-age atmosphere was caused by iron fertilization. It is argued that iron-rich dust is carried into the ocean by wind and water, where it stimulates the growth of algae that absorb more CO2. As the algae die and then sink permanently into the depths of the ocean, the CO2 also remains there like in a trap. Although there is clear evidence that dust input increased during the ice ages, the fertilization effect is controversial, at least for the Antarctic Ocean.

In a recent study, an international team of 38 researchers from 13 countries led by Dr. Michael Weber from the Institute for Geosciences at the University of Bonn investigated this question. As part of the Integrated Ocean Discovery Program (IODP), the team traveled to the Scotia Sea on the drillship "JOIDES Resolution" and spent two months in 2019 bringing up cores from the seafloor at depths of 3,000 to 4,000 meters. Weber: "We collected the highest-resolution and longest climate archive ever obtained near Antarctica and its main dust source, Patagonia."

1.5 million years of climate history

In the 200-meter-long deep-sea core U1537, the climate history of the last 1.5 million years was recorded in detail. This allows the reconstruction of the dust input to be nearly doubled, since Antarctic ice cores only cover the last 800,000 years. Current records from the deep ocean show that dust deposition during the ice ages was actually five to 15 times higher. This is also reflected in the ice cores.

However, the researchers found no evidence of a fertilization effect from dust in the Antarctic Ocean during the ice ages. Rather, the production of algae, for example, and thus carbon CO2 sequestration, was high only during warm periods when dust input into the Scotia Sea was low. This means that during cold periods, other processes prevented the CO2 captured in the ocean from escaping into the atmosphere and triggering warming. The main factors here are much more extensive sea ice cover, more intense stratification in the ocean, and reduced dynamics of the current systems, which contributed to a reduction in the CO2 content of the atmosphere during cold periods.

The opposing trends in dust deposition and oceanic productivity during the ice ages and interglacial periods of the Pleistocene are accompanied by long-term, gradual changes in the climate system in the southern polar region. Bioproductivity was particularly high during the interglacial periods of the last 400,000 years, but during the mid-Pleistocene transition 1.2 million to 700,000 years ago, it differed little from that during cold periods. As the transition progressed, the dust input covered larger and larger areas in the Southern Hemisphere. Abrupt changes continued to occur 900,000 years ago, indicating greater glaciation of Antarctica.

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