Jun 4, 2011

Heaviest elements yet join periodic table

Elements 114 and 116 have been officially added to the periodic table, becoming its heaviest members yet. They both exist for less than a second before decaying into lighter atoms, but they bring researchers a step closer to making even heavier elements that are predicted to be stable for decades or longer, forming a fabled "island of stability" in the periodic table.

Evidence for the two elements has been mounting for years. They were finally given official status as new elements on Wednesday, after a three-year review by the Joint Working Party on Discovery of Elements, a committee of scientists from the International Union of Pure and Applied Chemistry (IUPAC) and the International Union of Pure and Applied Physics (IUPAP).

Several teams have claimed to have produced element 114, starting in 1999. But the committee decided that a series of experiments reported by a collaboration of two teams in 2004 and 2006 provided the first convincing evidence. The same series of experiments is credited with producing evidence of element 116.
Slammed together

One of the collaborating groups was led by Yuri Oganessian at the Joint Institute for Nuclear Research (JINR) in Dubna, Russia, and the other by Ken Moody at the Lawrence Livermore National Laboratory in California.

The researchers forged the new heavy elements by slamming together the nuclei of lighter atoms at an accelerator at JINR. They made element 116 by bombarding targets made of the radioactive element curium, which has 96 protons in its nucleus, with calcium nuclei, which have 20 protons.

Nuclei of element 116 lasted only a few milliseconds before spitting out an alpha particle made of two protons and two neutrons and thereby decaying into nuclei of element 114. The team also made element 114 directly by firing calcium nuclei at plutonium targets, which have 94 protons in their nuclei.
Gone too soon

Element-114 nuclei decayed after about half a second into copernicium, which contains 112 protons, and is itself a very recent addition to the periodic table, having officially joined only in 2009. It was the pattern of time intervals between these decays, along with the energy of the alpha particles produced, that clinched the case for the elements' creation.

So what are elements 114 and 116 like? Unfortunately, their properties are still murky because the quantities produced were too small and existed too fleetingly for scientists to measure their chemical behaviour, such as what other elements they tend to react with.

"The lifetimes of these things have to be reasonably long so you can study the chemistry – meaning, pushing a minute," says Paul Karol of Carnegie Mellon University in Pittsburgh, who chaired the committee that approved the new elements.

Read more at New Scientist

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