Collision may have formed the Moon in mere hours, simulations reveal

Billions of years ago, a version of our Earth that looks very different than the one we live on today was hit by an object about the size of Mars, called Theia -- and out of that collision the Moon was formed. How exactly that formation occurred is a scientific puzzle researchers have studied for decades, without a conclusive answer.

Most theories claim the Moon formed out of the debris of this collision, coalescing in orbit over months or years. A new simulation puts forth a different theory -- the Moon may have formed immediately, in a matter of hours, when material from the Earth and Theia was launched directly into orbit after the impact.

"This opens up a whole new range of possible starting places for the Moon's evolution," said Jacob Kegerreis, a postdoctoral researcher at NASA's Ames Research Center in California's Silicon Valley, and lead author of the paper on these results published in The Astrophysical Journal Letters. "We went into this project not knowing exactly what the outcomes of these high-resolution simulations would be. So, on top of the big eye-opener that standard resolutions can give you misleading answers, it was extra exciting that the new results could include a tantalisingly Moon-like satellite in orbit."

The simulations used in this research are some of the most detailed of their kind, operating at the highest resolution of any simulation run to study the Moon's origins or other giant impacts. This extra computational power showed that lower-resolution simulations can miss out on important aspects of these kinds of collisions, allowing researchers to see new behaviors emerge in a way previous studies just couldn't see.

A Puzzle of Planetary History

Understanding the Moon's origins requires using what we know about the Moon -- our knowledge of its mass, orbit, and the precise analysis of lunar rock samples -- and coming up with scenarios that could lead to what we see today.

Previously prevailing theories could explain some aspects of the Moon's properties quite well, such as its mass and orbit, but with some major caveats. One outstanding mystery has been why the composition of the Moon is so similar to Earth's. Scientists can study the composition of a material based on its isotopic signature, a chemical clue to how and where an object was created. The lunar samples scientists have been able to study in labs show very similar isotopic signatures to rocks from Earth, unlike rocks from Mars or elsewhere in the solar system. This makes it likely that much of the material that makes up the Moon originally came from Earth.

In previous scenarios where Theia sprayed out into orbit and mixed with only a little material from Earth, it's less likely we'd see such strong similarities -- unless Theia was also isotopically similar to Earth, an unlikely coincidence. In this theory, more Earth material is used to create the Moon, particularly its outer layers, which could help to explain this similarity in composition.

There have been other theories proposed to explain these similarities in composition, such as the synestia model -- where the Moon is formed inside a swirl of vaporized rock from the collision -- but these arguably struggle to explain the Moon's current orbit.

This faster, single-stage formation theory offers a cleaner and more elegant explanation for both these outstanding issues. It could also give new ways to find answers for other unsolved mysteries. This scenario can put the Moon into a wide orbit with an interior that isn't fully molten, potentially explaining properties like the Moon's tilted orbit and thin crust -- making it one of the most enticing explanations for the Moon's origins yet.

Getting closer to confirming which of these theories is correct will require analysis of future lunar samples brought back to Earth for study from NASA's future Artemis missions. As scientists gain access to samples from other parts of the Moon and from deeper beneath the Moon's surface, they will be able to compare how real-world data matches up to these simulated scenarios, and what they indicate about how the Moon has evolved over its billions of years of history.

A Shared Origin

Beyond simply learning more about the Moon, these studies can bring us closer to understanding how our own Earth became the life-harboring world it is today.

"The more we learn about how the Moon came to be, the more we discover about the evolution of our own Earth," said Vincent Eke, a researcher at Durham University and a co-author on the paper. "Their histories are intertwined -- and could be echoed in the stories of other planets changed by similar or very different collisions."

The cosmos is filled with collisions -- impacts are an essential part of how planetary bodies form and evolve. On Earth, we know that the impact with Theia and other changes throughout its history are part of how it was able to gather the materials necessary for life. The better scientists can simulate and analyze what's at play in these collisions, the more prepared we are to understand how a planet could evolve to be habitable like our own Earth.

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The last 12,000 years show a more complex climate history than previously thought

We rely on climate models to predict the future, but models cannot be fully tested as climate observations rarely extend back more than 150 years. Understanding the Earth's past climate history across a longer period gives us an invaluable opportunity to test climate models on longer timescales and reduce uncertainties in climate predictions. In this context, changes in the average surface temperature of the Earth during the current interglacial Epoch, the Holocene (approximately the past 12,000 years), have been thoroughly debated over the past decades. Reconstructions of past temperature seem to indicate that global mean temperature showed a maximum around 6,000 years ago and has cooled until the onset of the current climate crisis during the industrial revolution.

Climate model simulations, on the other hand, suggest continuous warming since the start of the Holocene. In 2014, researchers named this major mismatch between models and past climate observations the "Holocene Temperature Conundrum."

In this new study, scientists used the largest available database of past temperature reconstructions extending back 12,000 years to carefully investigate the geographic pattern of temperature change during the Holocene. Olivier Cartapanis and colleagues find that, contrary to previously thought, there is no globally synchronous warm period during the Holocene. Instead, the warmest temperatures are found at different times not only in different regions but also between the ocean and on land. This questions how meaningful comparisons of the global mean temperature between reconstructions and models actually are.

According to the lead author Olivier Cartapanis, "the results challenge the paradigm of a Holocene Thermal Maximum occurring at the same time worldwide." And, while the warmest temperature was reached between 4,000 and 8,000 years ago in western Europe and northern America, the surface ocean temperature cooled since about 10,000 years ago at mid-high latitudes and remained stable in the tropics. The regional variability in the timing of maximum temperature suggests that high latitude insolation and ice extent played major roles in driving climate changes throughout the Holocene.

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Dinosaur-killing asteroid triggered global tsunami that scoured seafloor thousands of miles from impact site

The miles-wide asteroid that struck Earth 66 million years ago wiped out nearly all the dinosaurs and roughly three-quarters of the planet's plant and animal species.

It also triggered a monstrous tsunami with mile-high waves that scoured the ocean floor thousands of miles from the impact site on Mexico's Yucatan Peninsula, according to a new University of Michigan-led study.

The study, scheduled for online publication Oct. 4 in the journal AGU Advances, presents the first global simulation of the Chicxulub impact tsunami to be published in a peer-reviewed scientific journal. In addition, U-M researchers reviewed the geological record at more than 100 sites worldwide and found evidence that supports their models' predictions about the tsunami's path and power.

"This tsunami was strong enough to disturb and erode sediments in ocean basins halfway around the globe, leaving either a gap in the sedimentary records or a jumble of older sediments," said lead author Molly Range, who conducted the modeling study for a master's thesis under U-M physical oceanographer and study co-author Brian Arbic and U-M paleoceanographer and study co-author Ted Moore.

The review of the geological record focused on "boundary sections," marine sediments deposited just before or just after the asteroid impact and the subsequent K-Pg mass extinction, which closed the Cretaceous Period.

"The distribution of the erosion and hiatuses that we observed in the uppermost Cretaceous marine sediments are consistent with our model results, which gives us more confidence in the model predictions," said Range, who started the project as an undergraduate in Arbic's lab in the Department of Earth and Environmental Sciences.

The study authors calculated that the initial energy in the impact tsunami was up to 30,000 times larger than the energy in the December 2004 Indian Ocean earthquake tsunami, which killed more than 230,000 people and is one of the largest tsunamis in the modern record.

The team's simulations show that the impact tsunami radiated mainly to the east and northeast into the North Atlantic Ocean, and to the southwest through the Central American Seaway (which used to separate North America and South America) into the South Pacific Ocean.

In those basins and in some adjacent areas, underwater current speeds likely exceeded 20 centimeters per second (0.4 mph), a velocity that is strong enough to erode fine-grained sediments on the seafloor.

In contrast, the South Atlantic, the North Pacific, the Indian Ocean and the region that is today the Mediterranean were largely shielded from the strongest effects of the tsunami, according to the team's simulation. In those places, the modeled current speeds were likely less than the 20 cm/sec threshold.

For the review of the geological record, U-M's Moore analyzed published records of 165 marine boundary sections and was able to obtain usable information from 120 of them. Most of the sediments came from cores collected during scientific ocean-drilling projects.

The North Atlantic and South Pacific had the fewest sites with complete, uninterrupted K-Pg boundary sediments. In contrast, the largest number of complete K-Pg boundary sections were found in the South Atlantic, the North Pacific, the Indian Ocean and the Mediterranean.

"We found corroboration in the geological record for the predicted areas of maximal impact in the open ocean," said Arbic, professor of earth and environmental sciences who oversaw the project. "The geological evidence definitely strengthens the paper."

Of special significance, according to the authors, are outcrops of the K-Pg boundary on the eastern shores of New Zealand's north and south islands, which are more than 12,000 kilometers (7,500 miles) from the Yucatan impact site.

The heavily disturbed and incomplete New Zealand sediments, called olistostromal deposits, were originally thought to be the result of local tectonic activity. But given the age of the deposits and their location directly in the modeled pathway of the Chicxulub impact tsunami, the U-M-led research team suspects a different origin.

"We feel these deposits are recording the effects of the impact tsunami, and this is perhaps the most telling confirmation of the global significance of this event," Range said.

The modeling portion of the study used a two-stage strategy. First, a large computer program called a hydrocode simulated the chaotic first 10 minutes of the event, which included the impact, crater formation and initiation of the tsunami. That work was conducted by co-author Brandon Johnson of Purdue University.

Based on the findings of previous studies, the researchers modeled an asteroid that was 14 kilometers (8.7 miles) in diameter, moving at 12 kilometers per second (27,000 mph). It struck granitic crust overlain by thick sediments and shallow ocean waters, blasting a roughly 100-kilometer-wide (62-mile-wide) crater and ejecting dense clouds of soot and dust into the atmosphere.

Two and a half minutes after the asteroid struck, a curtain of ejected material pushed a wall of water outward from the impact site, briefly forming a 4.5-kilometer-high (2.8-mile-high) wave that subsided as the ejecta fell back to Earth.

Ten minutes after the projectile hit the Yucatan, and 220 kilometers (137 miles) from the point of impact, a 1.5-kilometer-high (0.93-mile-high) tsunami wave -- ring-shaped and outward-propagating -- began sweeping across the ocean in all directions, according to the U-M simulation.

At the 10-minute mark, the results of Johnson's iSALE hydrocode simulations were entered into two tsunami-propagation models, MOM6 and MOST, to track the giant waves across the ocean. MOM6 has been used to model tsunamis in the deep ocean, and NOAA uses the MOST model operationally for tsunami forecasts at its Tsunami Warning Centers.

"The big result here is that two global models with differing formulations gave almost identical results, and the geologic data on complete and incomplete sections are consistent with those results," said Moore, professor emeritus of earth and environmental sciences. "The models and the verification data match nicely."

According to the team's simulation:
 

• One hour after impact, the tsunami had spread outside the Gulf of Mexico and into the North Atlantic.
   
• Four hours after impact, the waves had passed through the Central American Seaway and into the Pacific.
   
• Twenty-four hours after impact, the waves had crossed most of the Pacific from the east and most of the Atlantic from the west and entered the Indian Ocean from both sides.
   
• By 48 hours after impact, significant tsunami waves had reached most of the world's coastlines.

For the current study, the researchers did not attempt to estimate the extent of coastal flooding caused by the tsunami.

However, their models indicate that open-ocean wave heights in the Gulf of Mexico would have exceeded 100 meters (328 feet), with wave heights of more than 10 meters (32.8 feet) as the tsunami approached North Atlantic coastal regions and parts of South America's Pacific coast.

As the tsunami neared those shorelines and encountered shallow bottom waters, wave heights would have increased dramatically through a process called shoaling. Current speeds would have exceeded the 20 centimeters per second threshold for most coastal areas worldwide.

"Depending on the geometries of the coast and the advancing waves, most coastal regions would be inundated and eroded to some extent," according to the study authors. "Any historically documented tsunamis pale in comparison with such global impact."

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Eating late increases hunger, decreases calories burned, and changes fat tissue

Obesity afflicts approximately 42 percent of the U.S. adult population and contributes to the onset of chronic diseases, including diabetes, cancer, and other conditions. While popular healthy diet mantras advise against midnight snacking, few studies have comprehensively investigated the simultaneous effects of late eating on the three main players in body weight regulation and thus obesity risk: regulation of calorie intake, the number of calories you burn, and molecular changes in fat tissue. A new study by investigators from Brigham and Women's Hospital, a founding member of the Mass General Brigham healthcare system, found that when we eat significantly impacts our energy expenditure, appetite, and molecular pathways in adipose tissue. Their results are published in Cell Metabolism.

"We wanted to test the mechanisms that may explain why late eating increases obesity risk," explained senior author Frank A. J. L. Scheer, PhD, Director of the Medical Chronobiology Program in the Brigham's Division of Sleep and Circadian Disorders. "Previous research by us and others had shown that late eating is associated with increased obesity risk, increased body fat, and impaired weight loss success. We wanted to understand why."

"In this study, we asked, 'Does the time that we eat matter when everything else is kept consistent?'" said first author Nina Vujovic, PhD, a researcher in the Medical Chronobiology Program in the Brigham's Division of Sleep and Circadian Disorders. "And we found that eating four hours later makes a significant difference for our hunger levels, the way we burn calories after we eat, and the way we store fat."

Vujovic, Scheer and their team studied 16 patients with a body mass index (BMI) in the overweight or obese range. Each participant completed two laboratory protocols: one with a strictly scheduled early meal schedule, and the other with the exact same meals, each scheduled about four hours later in the day. In the last two to three weeks before starting each of the in-laboratory protocols, participants maintained fixed sleep and wake schedules, and in the final three days before entering the laboratory, they strictly followed identical diets and meal schedules at home. In the lab, participants regularly documented their hunger and appetite, provided frequent small blood samples throughout the day, and had their body temperature and energy expenditure measured. To measure how eating time affected molecular pathways involved in adipogenesis, or how the body stores fat, investigators collected biopsies of adipose tissue from a subset of participants during laboratory testing in both the early and late eating protocols, to enable comparison of gene expression patterns/levels between these two eating conditions.

Results revealed that eating later had profound effects on hunger and appetite-regulating hormones leptin and ghrelin, which influence our drive to eat. Specifically, levels of the hormone leptin, which signals satiety, were decreased across the 24 hours in the late eating condition compared to the early eating conditions. When participants ate later, they also burned calories at a slower rate and exhibited adipose tissue gene expression towards increased adipogenesis and decreased lipolysis, which promote fat growth. Notably, these findings convey converging physiological and molecular mechanisms underlying the correlation between late eating and increased obesity risk.

Vujovic explains that these findings are not only consistent with a large body of research suggesting that eating later may increase one's likelihood of developing obesity, but they shed new light on how this might occur. By using a randomized crossover study, and tightly controlling for behavioral and environmental factors such as physical activity, posture, sleep, and light exposure, investigators were able to detect changes the different control systems involved in energy balance, a marker of how our bodies use the food we consume.

In future studies, Scheer's team aims to recruit more women to increase the generalizability of their findings to a broader population. While this study cohort included only five female participants, the study was set up to control for menstrual phase, reducing confounding but making recruiting women more difficult. Going forward, Scheer and Vujovic are also interested in better understanding the effects of the relationship between meal time and bedtime on energy balance.

"This study shows the impact of late versus early eating. Here, we isolated these effects by controlling for confounding variables like caloric intake, physical activity, sleep, and light exposure, but in real life, many of these factors may themselves be influenced by meal timing," said Scheer. "In larger scale studies, where tight control of all these factors is not feasible, we must at least consider how other behavioral and environmental variables alter these biological pathways underlying obesity risk. "

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Cosmic ray protons reveal new spectral structures at high energies

Discovered in 1912, cosmic rays have been studied extensively and our current understanding of them is compiled into what is called the Standard Model. Recently, this understanding has been challenged by the detection of unexpected spectral structures in the cosmic ray proton energy spectrum. Now, scientists take this further with high-statistics and low-uncertainty measurement of these protons over a broader energy range using the CALorimetric Electron Telescope, confirming the presence of such structures.

Cosmic rays constitute high-energy protons and atomic nuclei that originate from stars (both within our galaxy and from other galaxies) and are accelerated by supernovae and other high-energy astrophysical objects. Our current understanding of the Galactic cosmic ray energy spectrum suggests that it follows a power-law dependence, in that the spectral index of protons detected within a certain energy range goes down by power law as energy increases. But recent observations made using magnetic spectrometers for low energy levels and calorimeters for high energy levels has hinted at a deviation from this power-law variation, with the spectral index of protons becoming larger around an energy of few hundred GeV at energies up to 10 TeV. Following this "spectral hardening," characterized by a smaller absolute value of the spectral index, a "spectral softening" has been detected above 10 TeV using the CALorimetric Electron Telescope (CALET), a space telescope installed at the International Space Station. However, better measurements with high statistics and low uncertainty need to be performed over a broad energy spectrum for the confirmation of these spectral structures.

This is exactly what a team of international researchers led by Associate Professor Kazuyoshi Kobayashi from Waseda University in Japan set out to do. "With the data collected by CALET over roughly 6.2 years, we have put forth a detailed spectral structure of the cosmic ray protons. The novelty of our data lies in the high-statistics measurement over a broader energy range of 50 GeV to 60 TeV," elaborates Kobayashi. The findings of their study, which included contributions from Professor Emeritus Shoji Torii from Waseda University (PI, or Principal Investigator, of CALET project) and Professor Pier Simone Marrocchesi from University of Siena in Italy, was published in the journal Physical Review Letters on 1 September 2022.

The new observations confirmed the presence of spectral hardening and softening below and above 10 TeV, suggesting that the proton energy spectrum is not consistent with a single power law variation for the entire range. Moreover, the spectral softening starting at around 10 TeV is consistent with a previous measurement reported by the Dark Matter Particle Explorer (DAMPE) space telescope. Interestingly enough, the transition by spectral softening was found to be sharper than that by spectral hardening.

The variations and the uncertainty in the new CALET data were controlled using Monte Carlo simulations. The statistics was improved by a factor of around 2.2 and the spectral hardening feature was confirmed with a higher significance of more than 20 sigmas.

Talking about the significance of this research, Kobayashi remarks, "This result will significantly contribute to our understanding of cosmic ray acceleration by supernovae and the propagation mechanism of cosmic rays. The next step would be to extend our measurement of the proton spectra to even higher energies with reduced systematic uncertainties. This should be accompanied by a shift in the theoretical understanding to accommodate the new observations."

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Upcycling in the past: Viking beadmakers' secrets revealed

Ribe was an important trading town in the Viking Age. At the beginning of the 8th century, a trading place was established on the north side of the river Ribe, to which traders and craftsmen flocked from far and wide to manufacture and sell goods such as brooches, suit buckles, combs and coloured glass beads.

When glass became a scarce commodity in the Early Medieval time, coloured glass cubes -- so-called tesserae -- were torn down from mosaics in abandoned Roman and Byzantine temples, palaces and baths, transported North and traded at emporia towns such as Ribe, where the beadmakers melted them down in large vessels and shaped them into beads.

Until now, archaeologists have assumed that the pearl makers used the opaque white tesserae as raw material for the production of white, opaque beads.

Smart and sustainable production

And it is here that a geochemist and an archaeologist from Aarhus University together with a museum curator from Ribe have made a surprising discovery, which they have just published in the scientific journal Archaeological and Anthropological Sciences:

The chemical composition of white Viking beads from one of the earliest workshops showed that the glassmakers had found a more sustainable way to save time and wood for their furnaces: crush gold-gilded, transparent glass cubes, remelt them at low temperature, stir to trap air in the form of bubbles, and finally wrap the glass around an iron mandrel to form beads and voila! -- opaque white beads created in a short time using a minimum of resources.

The valuable ultra-thin sheets of gold stuck to the surface of the gold mosaic stone were of course salvaged by the glassmaker prior to remelting the glass, but the new findings show that some gold inevitably had ended up in the melting pot. Tiny drops of gold in the white beads, the many air holes (which is why the beads are opaque), as well as the fact that there are no chemical color tracers present, the researchers show that it was in fact the gold mosaic stones that was the raw material for the beads.

Such traces of gold were found not only in the white but also in the blue beads from the same workshop. Here the chemistry shows that the glassmaker's recipe consisted of a mixture of the blue and golden mosaic stones. Mixing them was necessary because the Roman blue mosaic stones contained high concentrations of chemical substances which made them opaque -- and therefore ideal for mosaics, but not for blue beads. By thus diluting the chemical substances, the result was the deep blue, transparent glass that we know from Viking Age beads.

Connoisseur craftsmanship

The bead maker in Ribe could instead have chosen to dilute the glass mixture with old shards from funnel beakers, which were also found in the workshop. But these turned out to be old, contaminated, Roman glass that had been remelted over and over again.

"And the glassmakers in Ribe were clearly connoisseurs who preferred the clearest glass they could get their hands on," says Gry Hoffmann Barfod from the Department of Geoscience at Aarhus University. She adds:

"For a geochemist, it has been a privilege to work with the fantastic material, and to discover how relevant the knowledge stored here is for our society today."

Interdisciplinary research

The interdisciplinary study was a collaboration between Gry Barfod, Søren Sindbæk, professor of archeology at the Danish National Research Foundation's Center for Urban Network Development (UrbNet) at Aarhus University, and museum curator Claus Feveile at the Museum of Southwest Jutland specializing in the Viking Age and Ribe's earliest history.

"The most outstanding achievements at the Ribe trading site were not just the products, but also the circular economy and their awareness to preserve limited resources" states professor Søren Sindbæk.

And museum curator Claus Feveile comments:

"These exciting results clearly show the potential of elucidating new facts about the vikings. By combining our high-resolution excavations with such chemical analyses I predict many more revelations in the near future."

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Scientists crack upcycling plastics to reduce greenhouse gas emissions

Scientists from the University of Illinois Urbana-Champaign, University of California, Santa Barbara, and Dow have developed a breakthrough process to transform the most widely produced plastic -- polyethylene (PE) -- into the second-most widely produced plastic, polypropylene (PP), which could reduce greenhouse gas emissions (GHG).

"The world needs more and better options for extracting the energy and molecular value from its waste plastics," said co-lead author Susannah Scott, Distinguished Professor and Mellichamp Chair of Sustainable Catalytic Processing at UC Santa Barbara. Conventional plastic recycling methods result in low-value plastic molecules and, thus, offer little incentive to recycle the mountains of plastic waste that have accumulated over the past several decades. But, Scott added, "turning polyethylene into propylene, which can then be used to make a new polymer, is how we start to build a circular economy for plastics."

"We started by conceptualizing this approach and demonstrated its promise first through theoretical modeling -- now we have proved that it can be done experimentally in a way that is scalable and potentially applicable to current industry demands," said co-lead author Damien Guironnet, a professor of chemical and biomolecular engineering at Illinois, who published the first study outlining the necessary catalytic reactions in 2020.

The new study published in the Journal of the American Chemical Society announces a series of coupled catalytic reactions that transform PE, which is #2 and #4 plastic that make up 29% of the world's plastic consumption, into the building block propylene that is the key ingredient to produce PP, also known as #5 plastic that accounts for close to 25% of the world's plastic consumption.

This study establishes a proof-of-concept for upcycling PE plastic with more than 95% selectivity into propylene. The researchers have built a reactor that creates a continuous flow of propylene that can be converted into PP easily using current technology -- making this discovery scalable and rapidly implementable.

"Our preliminary analysis suggests that if just 20% of the world's PE could be recovered and converted via this route, it could represent a potential savings of GHG emissions comparable to taking 3 million cars off the road," said Garrett Strong, a graduate student associated with the project.

The goal is to cut each very long PE molecule many times to obtain many small pieces, which are the propylene molecules. First, a catalyst removes hydrogen from the PE, creating a reactive location on the chain. Next, the chain is split in two at this location using a second catalyst, which caps the ends using ethylene. Finally, a third catalyst moves the reactive site along the PE chain so the process can be repeated. Eventually, all that is left are a large number of propylene molecules.

"Think of cutting a baguette in half, and then cutting precisely-sized pieces off the end of each half -- where the speed at which you cut controls the size of each slice," Guironnet said.

"Now that we have established the proof of concept, we can start to improve the efficiency of the process by designing catalysts that are faster and more productive, making it possible to scale up," Scott said. "Since our end-product is already compatible with current industry separation processes, better catalysts will make it possible to implement this breakthrough rapidly."

The work presented in this publication is highly complementary to a paper published in Science last week. Both groups used virgin plastics and similar chemistries. However, the Science team used a different process in an enclosed batch reactor, requiring much higher pressure -- which is energy intensive -- and the need to recycle more ethylene.

"If we are to upcycle a significant fraction of the over 100 million tons of plastic waste we generate each year, we need solutions that are highly scalable," Guironnet said. "Our team demonstrated the chemistry in a flow reactor we developed to produce propylene highly selectively and continuously. This is a key advance to address the immense volume of the problem that we are facing."

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Solar harvesting system has potential to generate solar power 24/7

The great inventor Thomas Edison once said, "So long as the sun shines, man will be able to develop power in abundance." His wasn't the first great mind to marvel at the notion of harnessing the power of the sun; for centuries inventors have been pondering and perfecting the way to harvest solar energy.

They've done an amazing job with photovoltaic cells which convert sunlight directly into energy. And still, with all the research, history and science behind it, there are limits to how much solar power can be harvested and used -- as its generation is restricted only to the daytime.

A University of Houston professor is continuing the historic quest, reporting on a new type of solar energy harvesting system that breaks the efficiency record of all existing technologies. And no less important, it clears the way to use solar power 24/7.

"With our architecture, the solar energy harvesting efficiency can be improved to the thermodynamic limit," reports Bo Zhao, Kalsi Assistant Professor of mechanical engineering and his doctoral student Sina Jafari Ghalekohneh in the journal Physical Review Applied. The thermodynamic limit is the absolute maximum theoretically possible conversion efficiency of sunlight into electricity.

Finding more efficient ways to harness solar energy is critical to transitioning to a carbon-free electric grid. According to a recent study by the U.S. Department of Energy Solar Energy Technologies Office and the National Renewable Energy Laboratory, solar could account for as much as 40% of the nation's electricity supply by 2035 and 45% by 2050, pending aggressive cost reductions, supportive policies and large-scale electrification.

How Does it Work?

Traditional solar thermophotovoltaics (STPV) rely on an intermediate layer to tailor sunlight for better efficiency. The front side of the intermediate layer (the side facing the sun) is designed to absorb all photons coming from the sun. In this way, solar energy is converted to thermal energy of the intermediate layer and elevates the temperature of the intermediate layer.

But the thermodynamic efficiency limit of STPVs, which has long been understood to be the blackbody limit (85.4%), is still far lower than the Landsberg limit (93.3%), the ultimate efficiency limit for solar energy harvesting.

"In this work, we show that the efficiency deficit is caused by the inevitable back emission of the intermediate layer towards the sun resulting from the reciprocity of the system. We propose nonreciprocal STPV systems that utilize an intermediate layer with nonreciprocal radiative properties," said Zhao. "Such a nonreciprocal intermediate layer can substantially suppress its back emission to the sun and funnel more photon flux towards the cell.

We show that, with such improvement, the nonreciprocal STPV system can reach the Landsberg limit, and practical STPV systems with single-junction photovoltaic cells can also experience a significant efficiency boost."

Besides improved efficiency, STPVs promise compactness and dispatchability (electricity that can be programmed on demand based on market needs).

In one important application scenario, STPVs can be coupled with an economical thermal energy storage unit to generate electricity 24/7.

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Webb, Hubble capture detailed views of DART impact

Two of NASA's Great Observatories, the James Webb Space Telescope and the Hubble Space Telescope, have captured views of a unique NASA experiment designed to intentionally smash a spacecraft into a small asteroid in the world's first-ever in-space test for planetary defense. These observations of NASA's Double Asteroid Redirection Test (DART) impact mark the first time that Webb and Hubble simultaneously observed the same celestial target.

On Sept. 26, 2022, at 7:14 pm EDT, DART intentionally crashed into Dimorphos, the asteroid moonlet in the double-asteroid system of Didymos. It was the world's first test of the kinetic impact mitigation technique, using a spacecraft to deflect an asteroid that poses no threat to Earth, and modifying the object's orbit. DART is a test for defending Earth against potential asteroid or comet hazards.

The coordinated Hubble and Webb observations are more than just an operational milestone for each telescope -- there are also key science questions relating to the makeup and history of our solar system that researchers can explore when combining the capabilities of these observatories.

"Webb and Hubble show what we've always known to be true at NASA: We learn more when we work together," said NASA Administrator Bill Nelson. "For the first time, Webb and Hubble have simultaneously captured imagery from the same target in the cosmos: an asteroid that was impacted by a spacecraft after a seven-million-mile journey. All of humanity eagerly awaits the discoveries to come from Webb, Hubble, and our ground-based telescopes -- about the DART mission and beyond."

Observations from Webb and Hubble together will allow scientists to gain knowledge about the nature of the surface of Dimorphos, how much material was ejected by the collision, and how fast it was ejected. Additionally, Webb and Hubble captured the impact in different wavelengths of light -- Webb in infrared and Hubble in visible. Observing the impact across a wide array of wavelengths will reveal the distribution of particle sizes in the expanding dust cloud, helping to determine whether it threw off lots of big chunks or mostly fine dust. Combining this information, along with ground-based telescope observations, will help scientists to understand how effectively a kinetic impact can modify an asteroid's orbit.

Webb Captures Impact Site Before and After Collision

Webb took one observation of the impact location before the collision took place, then several observations over the next few hours. Images from Webb's Near-Infrared Camera (NIRCam) show a tight, compact core, with plumes of material appearing as wisps streaming away from the center of where the impact took place.

Observing the impact with Webb presented the flight operations, planning, and science teams with unique challenges, because of the asteroid's speed of travel across the sky. As DART approached its target, the teams performed additional work in the weeks leading up to the impact to enable and test a method of tracking asteroids moving over three times faster than the original speed limit set for Webb.

"I have nothing but tremendous admiration for the Webb Mission Operations folks that made this a reality," said principal investigator Cristina Thomas of Northern Arizona University in Flagstaff, Arizona. "We have been planning these observations for years, then in detail for weeks, and I'm tremendously happy this has come to fruition."

Scientists also plan to observe the asteroid system in the coming months using Webb's Mid-Infrared Instrument (MIRI) and Webb's Near-Infrared Spectrograph (NIRSpec). Spectroscopic data will provide researchers with insight into the asteroid's chemical composition.

Webb observed the impact over five hours total and captured 10 images. The data was collected as part of Webb's Cycle 1 Guaranteed Time Observation Program 1245 led by Heidi Hammel of the Association of Universities for Research in Astronomy (AURA).

Hubble Images Show Movement of Ejecta After Impact

Hubble also captured observations of the binary system ahead of the impact, then again 15 minutes after DART hit the surface of Dimorphos. Images from Hubble's Wide Field Camera 3 show the impact in visible light. Ejecta from the impact appear as rays stretching out from the body of the asteroid. The bolder, fanned-out spike of ejecta to the left of the asteroid is in the general direction from which DART approached.

Some of the rays appear to be curved slightly, but astronomers need to take a closer look to determine what this could mean. In the Hubble images, astronomers estimate that the brightness of the system increased by three times after impact, and saw that brightness hold steady, even eight hours after impact.

Hubble plans to monitor the Didymos-Dimorphos system 10 more times over the next three weeks. These regular, relatively long-term observations as the ejecta cloud expands and fades over time will paint a more complete picture of the cloud's expansion from the ejection to its disappearance.

"When I saw the data, I was literally speechless, stunned by the amazing detail of the ejecta that Hubble captured," said Jian-Yang Li of the Planetary Science Institute in Tucson, Arizona, who led the Hubble observations. "I feel lucky to witness this moment and be part of the team that made this happen."

Hubble captured 45 images in the time immediately before and following DART's impact with Dimorphos. The Hubble data was collected as part of Cycle 29 General Observers Program 16674.

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Robotic drug capsule can deliver drugs to gut

One reason that it's so difficult to deliver large protein drugs orally is that these drugs can't pass through the mucus barrier that lines the digestive tract. This means that insulin and most other "biologic drugs" -- drugs consisting of proteins or nucleic acids -- have to be injected or administered in a hospital.

A new drug capsule developed at MIT may one day be able to replace those injections. The capsule has a robotic cap that spins and tunnels through the mucus barrier when it reaches the small intestine, allowing drugs carried by the capsule to pass into cells lining the intestine.

"By displacing the mucus, we can maximize the dispersion of the drug within a local area and enhance the absorption of both small molecules and macromolecules," says Giovanni Traverso, the Karl van Tassel Career Development Assistant Professor of Mechanical Engineering at MIT and a gastroenterologist at Brigham and Women's Hospital.

In a study appearing today in Science Robotics, the researchers demonstrated that they could use this approach to deliver insulin as well as vancomycin, an antibiotic peptide that currently has to be injected.

Shriya Srinivasan, a research affiliate at MIT's Koch Institute for Integrative Cancer Research and a junior fellow at the Society of Fellows at Harvard University, is the lead author of the study.

Tunneling through

For several years, Traverso's lab has been developing strategies to deliver protein drugs such as insulin orally. This is a difficult task because protein drugs tend to be broken down in acidic environment of the digestive tract, and they also have difficulty penetrating the mucus barrier that lines the tract.

To overcome those obstacles, Srinivasan came up with the idea of creating a protective capsule that includes a mechanism that can tunnel through mucus, just as tunnel boring machines drill into soil and rock.

"I thought that if we could tunnel through the mucus, then we could deposit the drug directly on the epithelium," she says. "The idea is that you would ingest this capsule and the outer layer would dissolve in the digestive tract, exposing all these features that start to churn through the mucus and clear it."

The "RoboCap" capsule, which is about the size of a multivitamin, carries its drug payload in a small reservoir at one end and carries the tunnelling features in its main body and surface. The capsule is coated with gelatin that can be tuned to dissolve at a specific pH.

When the coating dissolves, the change in pH triggers a tiny motor inside the RoboCap capsule to start spinning. This motion helps the capsule to tunnel into the mucus and displace it. The capsule is also coated with small studs that brush mucus away, similar to the action of a toothbrush.

The spinning motion also helps to erode the compartment that carries the drug, which is gradually released into the digestive tract.

"What the RoboCap does is transiently displace the initial mucus barrier and then enhance absorption by maximizing the dispersion of the drug locally," Traverso says. "By combining all of these elements, we're really maximizing our capacity to provide the optimal situation for the drug to be absorbed."

Enhanced delivery

In tests in animals, the researchers used this capsule to deliver either insulin or vancomycin, a large peptide antibiotic that is used to treat a broad range of infections, including skin infections as well as infections affecting orthopedic implants. With the capsule, the researchers found that they could deliver 20 to 40 times more drug than a similar capsule without the tunneling mechanism.

Once the drug is released from the capsule, the capsule itself passes through the digestive tract on its own. The researchers found no sign of inflammation or irritation in the digestive tract after the capsule passed through, and they also observed that the mucus layer reforms within a few hours after being displaced by the capsule.

Another approach that some researchers have used to enhance oral delivery of drugs is to give them along with additional drugs that help them cross through the intestinal tissue. However, these enhancers often only work with certain drugs. Because the MIT team's new approach relies solely on mechanical disruptions to the mucus barrier, it could potentially be applied to a broader set of drugs, Traverso says.

"Some of the chemical enhancers preferentially work with certain drug molecules," he says. "Using mechanical methods of administration can potentially enable more drugs to have enhanced absorption."

While the capsule used in this study released its payload in the small intestine, it could also be used to target the stomach or colon by changing the pH at which the gelatin coating dissolves. The researchers also plan to explore the possibility of delivering other protein drugs such as GLP1 receptor agonist, which is sometimes used to treat type 2 diabetes. The capsules could also be used to deliver topical drugs to treat ulcerative colitis and other inflammatory conditions by maximizing the local concentration of the drugs in the tissue to help treat the inflammation.

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